Zn(II) and Cu(II) complexes with the cluster-based ligand [Re 6(μ 3-Se)8(PEt3) 5(PTA)](SbF6)2 (PTA = 1,3,5-Triaza-7- phosphaadamantane)

Xiaoyan Tu; Gary S. Nichol; Zhiping Zheng

doi:10.1007/s10876-008-0206-5

Zn(II) and Cu(II) complexes with the cluster-based ligand [Re ₆(μ ₃-Se)₈(PEt₃) ₅(PTA)](SbF₆)₂ (PTA = 1,3,5-Triaza-7- phosphaadamantane)

Xiaoyan Tu, Gary S. Nichol, Zhiping Zheng

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Zn(II) and Cu(II) complexes of the cluster-based ligand [Re ₆(μ ₃-Se)₈(PEt₃) ₅(PTA)](SbF₆)₂ (PTA = 1,3,5-triaza-7- phosphaadamantane), {Zn[Re₆(μ ₃-Se) ₈(PEt₃)₅(PTA)](NO₃) ₃}(SbF₆) (1) and {Cu[Re₆(μ ₃-Se)₈(PEt₃)₅(PTA)](NO ₃)₃}(SbF₆) (2), were prepared and structurally characterized. They are the first N-coordinated Zn(II) and Cu(II) complexes wherein the PTA ligand displays an interesting and less-frequently observed P, N-coordination mode.

Original language	English (US)
Pages (from-to)	93-103
Number of pages	11
Journal	Journal of Cluster Science
Volume	20
Issue number	1
DOIs	https://doi.org/10.1007/s10876-008-0206-5
State	Published - Mar 2009

Keywords

Coordination
Crystal structure
Rhenium chalcogenide clusters
Water-soluble ligand

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Biochemistry
General Materials Science

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10.1007/s10876-008-0206-5

Cite this

@article{4f4743a8a24844dbbfa52b4489f943cb,

title = "Zn(II) and Cu(II) complexes with the cluster-based ligand [Re 6(μ 3-Se)8(PEt3) 5(PTA)](SbF6)2 (PTA = 1,3,5-Triaza-7- phosphaadamantane)",

abstract = "Zn(II) and Cu(II) complexes of the cluster-based ligand [Re 6(μ 3-Se)8(PEt3) 5(PTA)](SbF6)2 (PTA = 1,3,5-triaza-7- phosphaadamantane), {Zn[Re6(μ 3-Se) 8(PEt3)5(PTA)](NO3) 3}(SbF6) (1) and {Cu[Re6(μ 3-Se)8(PEt3)5(PTA)](NO 3)3}(SbF6) (2), were prepared and structurally characterized. They are the first N-coordinated Zn(II) and Cu(II) complexes wherein the PTA ligand displays an interesting and less-frequently observed P, N-coordination mode.",

keywords = "Coordination, Crystal structure, Rhenium chalcogenide clusters, Water-soluble ligand",

author = "Xiaoyan Tu and Nichol, {Gary S.} and Zhiping Zheng",

note = "Funding Information: Acknowledgements This research was supported in part by the National Science Foundation (CHE-0750530). The X-ray diffractometer was purchased through an NSF grant (CHE-96103474). We thank Xiangjian Kong, Xia{\textquoteright}men University, for crystallographic data collection of 2.",

year = "2009",

month = mar,

doi = "10.1007/s10876-008-0206-5",

language = "English (US)",

volume = "20",

pages = "93--103",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "1",

}

TY - JOUR

T1 - Zn(II) and Cu(II) complexes with the cluster-based ligand [Re 6(μ 3-Se)8(PEt3) 5(PTA)](SbF6)2 (PTA = 1,3,5-Triaza-7- phosphaadamantane)

AU - Tu, Xiaoyan

AU - Nichol, Gary S.

AU - Zheng, Zhiping

N1 - Funding Information: Acknowledgements This research was supported in part by the National Science Foundation (CHE-0750530). The X-ray diffractometer was purchased through an NSF grant (CHE-96103474). We thank Xiangjian Kong, Xia’men University, for crystallographic data collection of 2.

PY - 2009/3

Y1 - 2009/3

N2 - Zn(II) and Cu(II) complexes of the cluster-based ligand [Re 6(μ 3-Se)8(PEt3) 5(PTA)](SbF6)2 (PTA = 1,3,5-triaza-7- phosphaadamantane), {Zn[Re6(μ 3-Se) 8(PEt3)5(PTA)](NO3) 3}(SbF6) (1) and {Cu[Re6(μ 3-Se)8(PEt3)5(PTA)](NO 3)3}(SbF6) (2), were prepared and structurally characterized. They are the first N-coordinated Zn(II) and Cu(II) complexes wherein the PTA ligand displays an interesting and less-frequently observed P, N-coordination mode.

AB - Zn(II) and Cu(II) complexes of the cluster-based ligand [Re 6(μ 3-Se)8(PEt3) 5(PTA)](SbF6)2 (PTA = 1,3,5-triaza-7- phosphaadamantane), {Zn[Re6(μ 3-Se) 8(PEt3)5(PTA)](NO3) 3}(SbF6) (1) and {Cu[Re6(μ 3-Se)8(PEt3)5(PTA)](NO 3)3}(SbF6) (2), were prepared and structurally characterized. They are the first N-coordinated Zn(II) and Cu(II) complexes wherein the PTA ligand displays an interesting and less-frequently observed P, N-coordination mode.

KW - Coordination

KW - Crystal structure

KW - Rhenium chalcogenide clusters

KW - Water-soluble ligand

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DO - 10.1007/s10876-008-0206-5

M3 - Article

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SN - 1040-7278

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Zn(II) and Cu(II) complexes with the cluster-based ligand [Re ₆(μ ₃-Se)₈(PEt₃) ₅(PTA)](SbF₆)₂ (PTA = 1,3,5-Triaza-7- phosphaadamantane)

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 698626: Experimental Crystal Structure Determination

CCDC 698627: Experimental Crystal Structure Determination

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Zn(II) and Cu(II) complexes with the cluster-based ligand [Re 6(μ 3-Se)8(PEt3) 5(PTA)](SbF6)2 (PTA = 1,3,5-Triaza-7- phosphaadamantane)

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

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Datasets

CCDC 698626: Experimental Crystal Structure Determination

CCDC 698627: Experimental Crystal Structure Determination

Cite this

Zn(II) and Cu(II) complexes with the cluster-based ligand [Re ₆(μ ₃-Se)₈(PEt₃) ₅(PTA)](SbF₆)₂ (PTA = 1,3,5-Triaza-7- phosphaadamantane)