Volatile organic compound emissions from switchgrass cultivars used as biofuel crops

A. S.D. Eller; K. Sekimoto; J. B. Gilman; W. C. Kuster; J. A. de Gouw; R. K. Monson; M. Graus; E. Crespo; C. Warneke; R. Fall

doi:10.1016/j.atmosenv.2011.03.042

Volatile organic compound emissions from switchgrass cultivars used as biofuel crops

A. S.D. Eller, K. Sekimoto, J. B. Gilman, W. C. Kuster, J. A. de Gouw, R. K. Monson, M. Graus, E. Crespo, C. Warneke, R. Fall

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28 Scopus citations

Abstract

Volatile organic compound (VOC) emission rates during the growth and simulated harvest phases were determined for switchgrass (Panicum virgatum) using laboratory chamber measurements. Switchgrass is a candidate for use in second-generation (cellulosic) biofuel production and the acreage dedicated to its growth in the USA has already increased during the past decade. We estimate that the yearly emissions from switchgrass plantations, including both the growth and harvest phases will be on the order of 3 kg C ha^-1 methanol, 1 kg C ha^-1 acetaldehyde, 1 kg C ha^-1 acetone, 0.9 kg C ha^-1 monoterpenes, 0.5 kg C ha^-1 isoprene + another compound, most likely 1-penten-3-ol, 0.2 kg C ha^-1 hexenals, and 0.1 kg C ha^-1 hexenols. These emission rates are much lower than those expected from Eucalyptus or poplar plantations, which are other potential biofuel crops and have significantly higher VOC emissions, suggesting that the choice of species in the production of biofuels could have serious implications for regional air quality.

Original language	English (US)
Pages (from-to)	3333-3337
Number of pages	5
Journal	Atmospheric Environment
Volume	45
Issue number	19
DOIs	https://doi.org/10.1016/j.atmosenv.2011.03.042
State	Published - Jun 2011
Externally published	Yes

Keywords

Biofuel
Panicum virgatum
Switchgrass
Volatile organic compounds

ASJC Scopus subject areas

General Environmental Science
Atmospheric Science

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10.1016/j.atmosenv.2011.03.042

Cite this

@article{643575171220402c827870c4a557fbdc,

title = "Volatile organic compound emissions from switchgrass cultivars used as biofuel crops",

abstract = "Volatile organic compound (VOC) emission rates during the growth and simulated harvest phases were determined for switchgrass (Panicum virgatum) using laboratory chamber measurements. Switchgrass is a candidate for use in second-generation (cellulosic) biofuel production and the acreage dedicated to its growth in the USA has already increased during the past decade. We estimate that the yearly emissions from switchgrass plantations, including both the growth and harvest phases will be on the order of 3 kg C ha-1 methanol, 1 kg C ha-1 acetaldehyde, 1 kg C ha-1 acetone, 0.9 kg C ha-1 monoterpenes, 0.5 kg C ha-1 isoprene + another compound, most likely 1-penten-3-ol, 0.2 kg C ha-1 hexenals, and 0.1 kg C ha-1 hexenols. These emission rates are much lower than those expected from Eucalyptus or poplar plantations, which are other potential biofuel crops and have significantly higher VOC emissions, suggesting that the choice of species in the production of biofuels could have serious implications for regional air quality.",

keywords = "Biofuel, Panicum virgatum, Switchgrass, Volatile organic compounds",

author = "Eller, {A. S.D.} and K. Sekimoto and Gilman, {J. B.} and Kuster, {W. C.} and {de Gouw}, {J. A.} and Monson, {R. K.} and M. Graus and E. Crespo and C. Warneke and R. Fall",

note = "Funding Information: This work was funded by the USDA grant ( 2009-35112-05217 ) and the Climate Change and Air Quality programs of NOAA supported some of the laboratory work. Additional funding was provided by the Cooperative Institute for Environmental Sciences Visiting Fellows program . We thank Kyle Ward for assistance in growing the grasses described here, and the Manhattan Kansas, Plant Material Center (USDA) for providing switchgrass seed varieties.",

year = "2011",

month = jun,

doi = "10.1016/j.atmosenv.2011.03.042",

language = "English (US)",

volume = "45",

pages = "3333--3337",

journal = "Atmospheric Environment",

issn = "1352-2310",

publisher = "Elsevier Ltd",

number = "19",

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TY - JOUR

T1 - Volatile organic compound emissions from switchgrass cultivars used as biofuel crops

AU - Eller, A. S.D.

AU - Sekimoto, K.

AU - Gilman, J. B.

AU - Kuster, W. C.

AU - de Gouw, J. A.

AU - Monson, R. K.

AU - Graus, M.

AU - Crespo, E.

AU - Warneke, C.

AU - Fall, R.

N1 - Funding Information: This work was funded by the USDA grant ( 2009-35112-05217 ) and the Climate Change and Air Quality programs of NOAA supported some of the laboratory work. Additional funding was provided by the Cooperative Institute for Environmental Sciences Visiting Fellows program . We thank Kyle Ward for assistance in growing the grasses described here, and the Manhattan Kansas, Plant Material Center (USDA) for providing switchgrass seed varieties.

PY - 2011/6

Y1 - 2011/6

N2 - Volatile organic compound (VOC) emission rates during the growth and simulated harvest phases were determined for switchgrass (Panicum virgatum) using laboratory chamber measurements. Switchgrass is a candidate for use in second-generation (cellulosic) biofuel production and the acreage dedicated to its growth in the USA has already increased during the past decade. We estimate that the yearly emissions from switchgrass plantations, including both the growth and harvest phases will be on the order of 3 kg C ha-1 methanol, 1 kg C ha-1 acetaldehyde, 1 kg C ha-1 acetone, 0.9 kg C ha-1 monoterpenes, 0.5 kg C ha-1 isoprene + another compound, most likely 1-penten-3-ol, 0.2 kg C ha-1 hexenals, and 0.1 kg C ha-1 hexenols. These emission rates are much lower than those expected from Eucalyptus or poplar plantations, which are other potential biofuel crops and have significantly higher VOC emissions, suggesting that the choice of species in the production of biofuels could have serious implications for regional air quality.

AB - Volatile organic compound (VOC) emission rates during the growth and simulated harvest phases were determined for switchgrass (Panicum virgatum) using laboratory chamber measurements. Switchgrass is a candidate for use in second-generation (cellulosic) biofuel production and the acreage dedicated to its growth in the USA has already increased during the past decade. We estimate that the yearly emissions from switchgrass plantations, including both the growth and harvest phases will be on the order of 3 kg C ha-1 methanol, 1 kg C ha-1 acetaldehyde, 1 kg C ha-1 acetone, 0.9 kg C ha-1 monoterpenes, 0.5 kg C ha-1 isoprene + another compound, most likely 1-penten-3-ol, 0.2 kg C ha-1 hexenals, and 0.1 kg C ha-1 hexenols. These emission rates are much lower than those expected from Eucalyptus or poplar plantations, which are other potential biofuel crops and have significantly higher VOC emissions, suggesting that the choice of species in the production of biofuels could have serious implications for regional air quality.

KW - Biofuel

KW - Panicum virgatum

KW - Switchgrass

KW - Volatile organic compounds

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JO - Atmospheric Environment

JF - Atmospheric Environment

IS - 19

ER -

Volatile organic compound emissions from switchgrass cultivars used as biofuel crops

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