Abstract
Two mononuclear square-planar Cr(ii) complexes are reported, exhibiting field-induced slow magnetic relaxation. The axial zero-field splitting parameter was unambiguously determined by both a high-frequency/field electron paramagnetic resonance (HF-EPR) technique and magnetic measurements. This result represents the first observed single-molecule-magnet behavior in the square planar coordination geometry of any metal ions.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 17688-17691 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 51 |
| Issue number | 100 |
| DOIs | |
| State | Published - 2015 |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Catalysis
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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CCDC 1057925: Experimental Crystal Structure Determination
Deng, Y.-F. (Creator), Han, T. (Creator), Wang, Z. (Creator), Ouyang, Z. (Creator), Yin, B. (Creator), Zheng, Z. (Creator), Krzystek, J. (Creator) & Zheng, Y.-Z. (Creator), Cambridge Crystallographic Data Centre, 2015
DOI: 10.5517/cc14hvm3, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc14hvm3&sid=DataCite
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