Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor

Luca Beverina; Jie Fu; Amalia Leclercq; Egbert Zojer; Peter Pacher; Stephen Barlow; Eric W. Van Stryland; David J. Hagan; Jean Luc Brédas; Seth R. Marder

doi:10.1021/ja050688l

Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor

Luca Beverina
, Jie Fu
, Amalia Leclercq
, Egbert Zojer
, Peter Pacher
, Stephen Barlow
, Eric W. Van Stryland
, David J. Hagan
, Jean Luc Brédas
, Seth R. Marder

Research output: Contribution to journal › Article › peer-review

168 Scopus citations

Abstract

Three new dipolar chromophores based on a diaklyaminophenyl donor, a pyrrole auxiliary donor, a thiazole auxiliary acceptor, and strong heterocyclic acceptors have been synthesized. For one of these compounds we have measured a very large non-degenerate two-photon cross section of ca. 1500 GM in the near-IR telecommunications range using a pump-probe technique. Calculations indicate the cross section for degenerate two-photon absorption is likely to be ca. 60% of this value.

Original language	English (US)
Pages (from-to)	7282-7283
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	20
DOIs	https://doi.org/10.1021/ja050688l
State	Published - May 25 2005
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja050688l

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Beverina, L., Fu, J., Leclercq, A., Zojer, E., Pacher, P., Barlow, S., Van Stryland, E. W., Hagan, D. J., Brédas, J. L., & Marder, S. R. (2005). Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor. Journal of the American Chemical Society, 127(20), 7282-7283. https://doi.org/10.1021/ja050688l

Beverina, L, Fu, J, Leclercq, A, Zojer, E, Pacher, P, Barlow, S, Van Stryland, EW, Hagan, DJ, Brédas, JL & Marder, SR 2005, 'Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor', Journal of the American Chemical Society, vol. 127, no. 20, pp. 7282-7283. https://doi.org/10.1021/ja050688l

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abstract = "Three new dipolar chromophores based on a diaklyaminophenyl donor, a pyrrole auxiliary donor, a thiazole auxiliary acceptor, and strong heterocyclic acceptors have been synthesized. For one of these compounds we have measured a very large non-degenerate two-photon cross section of ca. 1500 GM in the near-IR telecommunications range using a pump-probe technique. Calculations indicate the cross section for degenerate two-photon absorption is likely to be ca. 60\% of this value.",

author = "Luca Beverina and Jie Fu and Amalia Leclercq and Egbert Zojer and Peter Pacher and Stephen Barlow and \{Van Stryland\}, \{Eric W.\} and Hagan, \{David J.\} and Br{\'e}das, \{Jean Luc\} and Marder, \{Seth R.\}",

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T1 - Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor

AU - Beverina, Luca

AU - Fu, Jie

AU - Leclercq, Amalia

AU - Zojer, Egbert

AU - Pacher, Peter

AU - Barlow, Stephen

AU - Van Stryland, Eric W.

AU - Hagan, David J.

AU - Brédas, Jean Luc

AU - Marder, Seth R.

PY - 2005/5/25

Y1 - 2005/5/25

N2 - Three new dipolar chromophores based on a diaklyaminophenyl donor, a pyrrole auxiliary donor, a thiazole auxiliary acceptor, and strong heterocyclic acceptors have been synthesized. For one of these compounds we have measured a very large non-degenerate two-photon cross section of ca. 1500 GM in the near-IR telecommunications range using a pump-probe technique. Calculations indicate the cross section for degenerate two-photon absorption is likely to be ca. 60% of this value.

AB - Three new dipolar chromophores based on a diaklyaminophenyl donor, a pyrrole auxiliary donor, a thiazole auxiliary acceptor, and strong heterocyclic acceptors have been synthesized. For one of these compounds we have measured a very large non-degenerate two-photon cross section of ca. 1500 GM in the near-IR telecommunications range using a pump-probe technique. Calculations indicate the cross section for degenerate two-photon absorption is likely to be ca. 60% of this value.

UR - https://www.scopus.com/pages/publications/21144476845

UR - https://www.scopus.com/pages/publications/21144476845#tab=citedBy

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SP - 7282

EP - 7283

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 20

ER -

Two-photon absorption at telecommunications wavelengths in a dipolar chromophore with a pyrrole auxiliary donor and thiazole auxiliary acceptor

Abstract

ASJC Scopus subject areas

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