Trend of shape resonance-induced features in the angular distribution parameter as a function of photon energy for carbon, silicon and germanium tetrac

M. N. Piancastelli; P. R. Keller; J. W. Taylor; F. A. Grimm; T. A. Carlson; M. O. Krause; D. Lichtenberger

doi:10.1016/0368-2048(84)80065-1

Trend of shape resonance-induced features in the angular distribution parameter as a function of photon energy for carbon, silicon and germanium tetrac

M. N. Piancastelli, P. R. Keller, J. W. Taylor, F. A. Grimm, T. A. Carlson, M. O. Krause, D. Lichtenberger

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The angular distribution parameter as a function of photon energy, β(hν), has been measured in the 13-27 e V range using synchrotron radiation for the five valence orbitais in silicon and germanium tetrachlorides. The results have been compared with those previously reported for carbon tetrachloride. In particular, the trend of shape resonanceinduced features has been followed along the valence isoelectronic series CCl₄-SiCl₄-GeCl₄ for the 1e and 2t₂ orbitals. As the atomic number of the central atom increases, the shape resonances move toward the threshold ionization energy for a particular molecular orbital.

Original language	English (US)
Pages (from-to)	205-214
Number of pages	10
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	34
Issue number	3
DOIs	https://doi.org/10.1016/0368-2048(84)80065-1
State	Published - 1984

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Radiation
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry

Access to Document

10.1016/0368-2048(84)80065-1

Cite this

Piancastelli, M. N., Keller, P. R., Taylor, J. W., Grimm, F. A., Carlson, T. A., Krause, M. O., & Lichtenberger, D. (1984). Trend of shape resonance-induced features in the angular distribution parameter as a function of photon energy for carbon, silicon and germanium tetrac. Journal of Electron Spectroscopy and Related Phenomena, 34(3), 205-214. https://doi.org/10.1016/0368-2048(84)80065-1

Trend of shape resonance-induced features in the angular distribution parameter as a function of photon energy for carbon, silicon and germanium tetrac. / Piancastelli, M. N.; Keller, P. R.; Taylor, J. W. et al.
In: Journal of Electron Spectroscopy and Related Phenomena, Vol. 34, No. 3, 1984, p. 205-214.

Research output: Contribution to journal › Article › peer-review

Piancastelli, MN, Keller, PR, Taylor, JW, Grimm, FA, Carlson, TA, Krause, MO & Lichtenberger, D 1984, 'Trend of shape resonance-induced features in the angular distribution parameter as a function of photon energy for carbon, silicon and germanium tetrac', Journal of Electron Spectroscopy and Related Phenomena, vol. 34, no. 3, pp. 205-214. https://doi.org/10.1016/0368-2048(84)80065-1

@article{d524ff835f38421b86f723eaf5095223,

title = "Trend of shape resonance-induced features in the angular distribution parameter as a function of photon energy for carbon, silicon and germanium tetrac",

abstract = "The angular distribution parameter as a function of photon energy, β(hν), has been measured in the 13-27 e V range using synchrotron radiation for the five valence orbitais in silicon and germanium tetrachlorides. The results have been compared with those previously reported for carbon tetrachloride. In particular, the trend of shape resonanceinduced features has been followed along the valence isoelectronic series CCl4-SiCl4-GeCl4 for the 1e and 2t2 orbitals. As the atomic number of the central atom increases, the shape resonances move toward the threshold ionization energy for a particular molecular orbital.",

author = "Piancastelli, {M. N.} and Keller, {P. R.} and Taylor, {J. W.} and Grimm, {F. A.} and Carlson, {T. A.} and Krause, {M. O.} and D. Lichtenberger",

note = "Funding Information: Researchs ponsoredb y WisconsinA lumni ResearchF oundation and NSF grants DMR79-24555 and CHE81-21205. The Synchrotron Radiation Center is operated under NSF grant DMR77-21888. Support at Oak Ridge is provided by the Division of Chemical Sciences,O ffice of Basic Energy Sciences,U .S. Departmento f Energy underc ontractW -7405-eng-26 with the Union CarbideC orporation.M .N.P. was a CNR sponsoredF ellow, 1982-83.",

year = "1984",

doi = "10.1016/0368-2048(84)80065-1",

language = "English (US)",

volume = "34",

pages = "205--214",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - Trend of shape resonance-induced features in the angular distribution parameter as a function of photon energy for carbon, silicon and germanium tetrac

AU - Piancastelli, M. N.

AU - Keller, P. R.

AU - Taylor, J. W.

AU - Grimm, F. A.

AU - Carlson, T. A.

AU - Krause, M. O.

AU - Lichtenberger, D.

N1 - Funding Information: Researchs ponsoredb y WisconsinA lumni ResearchF oundation and NSF grants DMR79-24555 and CHE81-21205. The Synchrotron Radiation Center is operated under NSF grant DMR77-21888. Support at Oak Ridge is provided by the Division of Chemical Sciences,O ffice of Basic Energy Sciences,U .S. Departmento f Energy underc ontractW -7405-eng-26 with the Union CarbideC orporation.M .N.P. was a CNR sponsoredF ellow, 1982-83.

PY - 1984

Y1 - 1984

N2 - The angular distribution parameter as a function of photon energy, β(hν), has been measured in the 13-27 e V range using synchrotron radiation for the five valence orbitais in silicon and germanium tetrachlorides. The results have been compared with those previously reported for carbon tetrachloride. In particular, the trend of shape resonanceinduced features has been followed along the valence isoelectronic series CCl4-SiCl4-GeCl4 for the 1e and 2t2 orbitals. As the atomic number of the central atom increases, the shape resonances move toward the threshold ionization energy for a particular molecular orbital.

AB - The angular distribution parameter as a function of photon energy, β(hν), has been measured in the 13-27 e V range using synchrotron radiation for the five valence orbitais in silicon and germanium tetrachlorides. The results have been compared with those previously reported for carbon tetrachloride. In particular, the trend of shape resonanceinduced features has been followed along the valence isoelectronic series CCl4-SiCl4-GeCl4 for the 1e and 2t2 orbitals. As the atomic number of the central atom increases, the shape resonances move toward the threshold ionization energy for a particular molecular orbital.

UR - http://www.scopus.com/inward/record.url?scp=0000973991&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000973991&partnerID=8YFLogxK

U2 - 10.1016/0368-2048(84)80065-1

DO - 10.1016/0368-2048(84)80065-1

M3 - Article

AN - SCOPUS:0000973991

SN - 0368-2048

VL - 34

SP - 205

EP - 214

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

IS - 3

ER -

Trend of shape resonance-induced features in the angular distribution parameter as a function of photon energy for carbon, silicon and germanium tetrac

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this