The rotational spectrum and theoretical study of a dinuclear complex, MnRe(CO) 10

Chakree Tanjaroon; Kristen S. Keck; Stephen G. Kukolich; Michael H. Palmer; Martyn F. Guest

doi:10.1063/1.1637589

The rotational spectrum and theoretical study of a dinuclear complex, MnRe(CO) ₁₀

Chakree Tanjaroon, Kristen S. Keck, Stephen G. Kukolich, Michael H. Palmer, Martyn F. Guest

Chemistry and Biochemistry

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6 Scopus citations

Abstract

The rotational spectrum of a dinuclear complex was studied using high-resolution pulsed beam microwave spectrometers. The rotational spectrum of MnRe(CO) ₁₀ were measured and analyzed to obtain the gas phase molecular parameters of the complex. It was observed that the solid phase could be due to the presence of the crystal packing forces in the crystal. The results suggest that the Mn-Re bond is slightly larger than the sum of the covalent radii.

Original language	English (US)
Pages (from-to)	4715-4725
Number of pages	11
Journal	Journal of Chemical Physics
Volume	120
Issue number	10
DOIs	https://doi.org/10.1063/1.1637589
State	Published - Mar 8 2004

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "The rotational spectrum of a dinuclear complex was studied using high-resolution pulsed beam microwave spectrometers. The rotational spectrum of MnRe(CO) 10 were measured and analyzed to obtain the gas phase molecular parameters of the complex. It was observed that the solid phase could be due to the presence of the crystal packing forces in the crystal. The results suggest that the Mn-Re bond is slightly larger than the sum of the covalent radii.",

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AU - Tanjaroon, Chakree

AU - Keck, Kristen S.

AU - Kukolich, Stephen G.

AU - Palmer, Michael H.

AU - Guest, Martyn F.

PY - 2004/3/8

Y1 - 2004/3/8

N2 - The rotational spectrum of a dinuclear complex was studied using high-resolution pulsed beam microwave spectrometers. The rotational spectrum of MnRe(CO) 10 were measured and analyzed to obtain the gas phase molecular parameters of the complex. It was observed that the solid phase could be due to the presence of the crystal packing forces in the crystal. The results suggest that the Mn-Re bond is slightly larger than the sum of the covalent radii.

AB - The rotational spectrum of a dinuclear complex was studied using high-resolution pulsed beam microwave spectrometers. The rotational spectrum of MnRe(CO) 10 were measured and analyzed to obtain the gas phase molecular parameters of the complex. It was observed that the solid phase could be due to the presence of the crystal packing forces in the crystal. The results suggest that the Mn-Re bond is slightly larger than the sum of the covalent radii.

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The rotational spectrum and theoretical study of a dinuclear complex, MnRe(CO) ₁₀

Abstract

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