@inbook{52405ac2bac8472e863316792e33e243,
title = "The Realization of an Oxidative Dearomatization-Intramolecular Diels-Alder Route to Vinigrol",
abstract = "Detailed in this chapter is the Njardarson group vinigrol total synthesis saga. Even though the Njardarson group synthetic strategy had undergone multiple modifications over time, it remained faithful to several key reaction design elements, namely: (a) oxidative dearomatization/Diels-Alder cascade, (b) radical or palladium cascade, (c) creation of a tetracyclic cage for substrate control purposes, and (d) a late-stage C-C bond fragmentation reaction to unravel the vinigrol core. The saga begins with the earliest oxidative dearomatization explorations followed by detailed descriptions of the modifications that were made in response to the obstacles encountered en route to the completed total synthesis of vinigrol.",
keywords = "Adler-Becker oxidation, Allylic oxidation, Diels-Alder, Fragmentation, Hypervalent iodide, Lead(IV) acetate, Oxidative dearomatization, Palladium cyclization, Radical cyclization, Samarium diiodide, Selenium dioxide, Trifluoroethyl ether, Vinigrol, Wessely oxidation",
author = "Cristian Draghici and Njardarson, {Jon T.}",
note = "Funding Information: We thank the NIH-NIGMS (RO1 GM086584) and University of Arizona for generous financial support. Special thanks to Dr. Jason G.M. Morton for bravely taking on the vinigrol project and then handing it on to Qingliang Yang, Dr. Cristian Draghici, and Dr. Fang Li to take it all the way to the finish line. Publisher Copyright: {\textcopyright} 2015 Elsevier Ltd. All rights reserved.",
year = "2015",
doi = "10.1016/B978-0-08-100023-6.00011-7",
language = "English (US)",
series = "Strategies and Tactics in Organic Synthesis",
publisher = "Academic Press Inc.",
pages = "335--376",
booktitle = "Strategies and Tactics in Organic Synthesis",
}