The pure rotational spectrum of TiF (X4Φr): 3 d transition metal fluorides revisited

P. M. Sheridan; S. K. McLamarrah; L. M. Ziurys

doi:10.1063/1.1615753

The pure rotational spectrum of TiF (X⁴Φ_r): 3 d transition metal fluorides revisited

P. M. Sheridan, S. K. McLamarrah, L. M. Ziurys

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The first measurement of the pure rotational spectrum of the TiF radical using millimeter/sub-mm direct absorption methods is presented. The given data is modeled using a Hund's case (a) effective Hamiltonian, leading to the determination of rotational, fine structure, and hyperfine parameters. This paper presents the results, interpret the constants and discuss their implications for bonding in 3d transition metal fluorides.

Original language	English (US)
Pages (from-to)	9496-9503
Number of pages	8
Journal	Journal of Chemical Physics
Volume	119
Issue number	18
DOIs	https://doi.org/10.1063/1.1615753
State	Published - Nov 8 2003

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1615753

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abstract = "The first measurement of the pure rotational spectrum of the TiF radical using millimeter/sub-mm direct absorption methods is presented. The given data is modeled using a Hund's case (a) effective Hamiltonian, leading to the determination of rotational, fine structure, and hyperfine parameters. This paper presents the results, interpret the constants and discuss their implications for bonding in 3d transition metal fluorides.",

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AB - The first measurement of the pure rotational spectrum of the TiF radical using millimeter/sub-mm direct absorption methods is presented. The given data is modeled using a Hund's case (a) effective Hamiltonian, leading to the determination of rotational, fine structure, and hyperfine parameters. This paper presents the results, interpret the constants and discuss their implications for bonding in 3d transition metal fluorides.

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The pure rotational spectrum of TiF (X⁴Φ_r): 3 d transition metal fluorides revisited

Abstract

ASJC Scopus subject areas

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