The pure rotational spectrum of NaC in its X 4Σ- state: Observation and interpretation

P. M. Sheridan; J. Xin; L. M. Ziurys; Sara A. Beaton; Stephen M. Kermode; John M. Brown

doi:10.1063/1.1457441

The pure rotational spectrum of NaC in its X ⁴Σ^- state: Observation and interpretation

P. M. Sheridan, J. Xin, L. M. Ziurys, Sara A. Beaton, Stephen M. Kermode, John M. Brown

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Abstract

The pure rotational spectrum of NaC in its X ⁴σ^- state was recorded using millimeter/submillimeter-wave absorption spectroscopy. NaC was synthesized from the reaction of sodium vapor with methane gas in a dc discharge. Phase-locked Gunn oscillators and Schottky diode multipliers were used in combination to produce radiation in the 65-540 GHz range. Analysis of the rotational spectrum showed the development of uncertainty in the determination of spin-spin parameter in ⁴σ states.

Original language	English (US)
Pages (from-to)	5544-5550
Number of pages	7
Journal	Journal of Chemical Physics
Volume	116
Issue number	13
DOIs	https://doi.org/10.1063/1.1457441
State	Published - Apr 1 2002

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "The pure rotational spectrum of NaC in its X 4σ- state was recorded using millimeter/submillimeter-wave absorption spectroscopy. NaC was synthesized from the reaction of sodium vapor with methane gas in a dc discharge. Phase-locked Gunn oscillators and Schottky diode multipliers were used in combination to produce radiation in the 65-540 GHz range. Analysis of the rotational spectrum showed the development of uncertainty in the determination of spin-spin parameter in 4σ states.",

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T2 - Observation and interpretation

AU - Sheridan, P. M.

AU - Xin, J.

AU - Ziurys, L. M.

AU - Beaton, Sara A.

AU - Kermode, Stephen M.

AU - Brown, John M.

PY - 2002/4/1

Y1 - 2002/4/1

N2 - The pure rotational spectrum of NaC in its X 4σ- state was recorded using millimeter/submillimeter-wave absorption spectroscopy. NaC was synthesized from the reaction of sodium vapor with methane gas in a dc discharge. Phase-locked Gunn oscillators and Schottky diode multipliers were used in combination to produce radiation in the 65-540 GHz range. Analysis of the rotational spectrum showed the development of uncertainty in the determination of spin-spin parameter in 4σ states.

AB - The pure rotational spectrum of NaC in its X 4σ- state was recorded using millimeter/submillimeter-wave absorption spectroscopy. NaC was synthesized from the reaction of sodium vapor with methane gas in a dc discharge. Phase-locked Gunn oscillators and Schottky diode multipliers were used in combination to produce radiation in the 65-540 GHz range. Analysis of the rotational spectrum showed the development of uncertainty in the determination of spin-spin parameter in 4σ states.

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 13

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The pure rotational spectrum of NaC in its X ⁴Σ^- state: Observation and interpretation

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