The presolar grain inventory of fine-grained chondrule rims in the Mighei-type (CM) chondrites

We investigated the inventory of presolar silicate, oxide, and silicon carbide (SiC) grains of fine-grained chondrule rims in six Mighei-type (CM) carbonaceous chondrites (Banten, Jbilet Winselwan, Maribo, Murchison, Murray and Yamato 791198), and the CM-related carbonaceous chondrite Sutter's Mill. Sixteen O-anomalous grains (nine silicates, six oxides) were detected, corresponding to a combined matrix-normalized abundance of ~18 ppm, together with 21 presolar SiC grains (~42 ppm). Twelve of the O-rich grains are enriched in ¹⁷O, and could originate from low-mass asymptotic giant branch stars. One grain is enriched in ¹⁷O and significantly depleted in ¹⁸O, indicative of additional cool bottom processing or hot bottom burning in its stellar parent, and three grains are of likely core-collapse supernova origin showing enhanced ¹⁸O/¹⁶O ratios relative to the solar system ratio. We find a presolar silicate/oxide ratio of 1.5, significantly lower than the ratios typically observed for chondritic meteorites. This may indicate a higher degree of aqueous alteration in the studied meteorites, or hint at a heterogeneous distribution of presolar silicates and oxides in the solar nebula. Nevertheless, the low O-anomalous grain abundance is consistent with aqueous alteration occurring in the protosolar nebula and/or on the respective parent bodies. Six O-rich presolar grains were studied by Auger Electron Spectroscopy, revealing two Fe-rich silicates, one forsterite-like Mg-rich silicate, two Al-oxides with spinel-like compositions, and one Fe-(Mg-)oxide. Scanning electron and transmission electron microscopic investigation of a relatively large silicate grain (490 nm × 735 nm) revealed that it was crystalline åkermanite (Ca₂Mg[Si₂O₇]) or a an åkermanite-diopside (MgCaSi₂O₆) intergrowth.