The lowest singlet and triplet states of the oxyallyl diradical

Takatoshi Ichino; Stephanie M. Villano; Adam J. Gianola; Daniel J. Goebbert; Andrei Sanov; Luis Velarde; Stephen J. Blanksby; Xin Zhou; David A. Hrovat; Weston Thatcher Borden; W. Carl Lineberger

doi:10.1002/anie.200904417

The lowest singlet and triplet states of the oxyallyl diradical

Takatoshi Ichino, Stephanie M. Villano, Adam J. Gianola, Daniel J. Goebbert, Andrei Sanov, Luis Velarde, Stephen J. Blanksby, Xin Zhou, David A. Hrovat, Weston Thatcher Borden, W. Carl Lineberger

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

Small S-T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.

Original language	English (US)
Pages (from-to)	8509-8511
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	45
DOIs	https://doi.org/10.1002/anie.200904417
State	Published - Oct 26 2009

Keywords

Oxyallyl compounds
Photoelectron spectroscopy
Radicals
Reactive intermediates

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.200904417

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abstract = "Small S-T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.",

keywords = "Oxyallyl compounds, Photoelectron spectroscopy, Radicals, Reactive intermediates",

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AU - Ichino, Takatoshi

AU - Villano, Stephanie M.

AU - Gianola, Adam J.

AU - Goebbert, Daniel J.

AU - Sanov, Andrei

AU - Velarde, Luis

AU - Blanksby, Stephen J.

AU - Zhou, Xin

AU - Hrovat, David A.

AU - Borden, Weston Thatcher

AU - Carl Lineberger, W.

PY - 2009/10/26

Y1 - 2009/10/26

N2 - Small S-T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.

AB - Small S-T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.

KW - Oxyallyl compounds

KW - Photoelectron spectroscopy

KW - Radicals

KW - Reactive intermediates

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The lowest singlet and triplet states of the oxyallyl diradical

Abstract

Keywords

ASJC Scopus subject areas

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