Equilibrium constants for the substitution of co-ordinated H2O by the malonitrile anion, CH(CN)2-, in the CoIII corrinoids aquocobalamin and diaquocobinamide have been determined in aqueous solution at 25 °C as log K(dm3 mol-1) = 7.4 and ca. 11.5 respectively.
|Original language||English (US)|
|Number of pages||4|
|Journal||Journal of the Chemical Society, Dalton Transactions|
|State||Published - 1985|
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