The Bohr-Sommerfeld theory of hydrogen and hydrogen-like atoms

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Niels Bohr's model of the hydrogen and hydrogen-like atoms, in which the electron is allowed to revolve in certain circular orbits around the nucleus, was extended by Arnold Sommerfeld to allow for the possibility of elliptical orbits. Each elliptical orbit was constrained by two quantization conditions specified by a positive integer nφ and a non-negative integer nr. If, in the presence of the attractive Coulomb force between the electron and the nucleus, the dynamics of the atom were taken to be governed by the Newtonian laws of motion, the energy of the two-particle system was found to be a function of the positive integer n = nr + nφ. The atomic energy levels thus exhibited an n-fold degeneracy, which would be lifted in the presence of external electric or magnetic fields, thus accounting for the fine-structure of the spectral lines emitted by the atom - phenomena observed, respectively, in the Stark effect and the Zeeman effect. Sommerfeld also examined the behavior of his elliptical orbits by allowing the revolving electron to obey Einstein's relativistic dynamics. In this case, the energy-level degeneracies were lifted (even in the absence of external perturbations), and the elliptical orbits were found to precess around the nucleus - similarly to the precession of, say, the orbit of the planet Mercury around the Sun. What is astonishing about Sommerfeld's relativistic expression of the energy as a function of nφ and nr is that it is precisely the same expression as obtained for hydrogen and hydrogen-like atoms from Dirac's equation, which came more than a decade later. Recall that the spin of the electron was not yet discovered when Sommerfeld developed his model, and that in Dirac's fully-relativistic quantum mechanics, the spectral fine-structure arises from the coupling of the electron's spin to its orbital motion. The present paper provides a streamlined yet detailed account of Sommerfeld's elliptical orbits in hopes of bringing about a deeper appreciation for the miraculous coincidence of Sommerfeld's result with that derived from Dirac's equation.

Original languageEnglish (US)
Title of host publicationSpintronics XVIII
EditorsJean-Eric Wegrowe, Joseph S. Friedman, Manijeh Razeghi, Henri Jaffres
PublisherSPIE
ISBN (Electronic)9781510690806
DOIs
StatePublished - Sep 18 2025
Event18th Spintronics - San Diego, United States
Duration: Aug 3 2025Aug 7 2025

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume13586
ISSN (Print)0277-786X
ISSN (Electronic)1996-756X

Conference

Conference18th Spintronics
Country/TerritoryUnited States
CitySan Diego
Period8/3/258/7/25

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Instrumentation
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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