Abstract
Restrain and release: A one-pot MukaiyamaMichael/epoxidation sequence introduced three stereocenters, an intramolecular isocyanate trapping produced a rigid 10-membered cyclic carbamate, and the selective opening of the cyclic carbamate was used to reveal the fully constructed natural product.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 8682-8685 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 49 |
| Issue number | 46 |
| DOIs | |
| State | Published - Nov 8 2010 |
| Externally published | Yes |
Keywords
- DielsAlder reaction
- MukaiyamaMichael reaction
- amides
- mycalamideB
- natural products
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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