Synthesis of: Z -alkenes via visible light promoted photocatalytic e → Z isomerization under metal-free conditions

Wenbin Cai; Huaqiang Fan; Dazhong Ding; Yongqiang Zhang; Wei Wang

doi:10.1039/c7cc07984b

Synthesis of: Z -alkenes via visible light promoted photocatalytic e → Z isomerization under metal-free conditions

Wenbin Cai, Huaqiang Fan, Dazhong Ding, Yongqiang Zhang, Wei Wang

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

A green approach for the synthesis of thermodynamically less stable Z-alkenes has been presented through the exploration of visible light promoted photocatalytic E-to-Z isomerization. This protocol features metal-free conditions, which is operationally simple, remarkably clean, and allows the synthesis of both electron-rich and electron-deficient Z-alkenes with diverse functional groups.

Original language	English (US)
Pages (from-to)	12918-12921
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	96
DOIs	https://doi.org/10.1039/c7cc07984b
State	Published - 2017
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A green approach for the synthesis of thermodynamically less stable Z-alkenes has been presented through the exploration of visible light promoted photocatalytic E-to-Z isomerization. This protocol features metal-free conditions, which is operationally simple, remarkably clean, and allows the synthesis of both electron-rich and electron-deficient Z-alkenes with diverse functional groups.",

author = "Wenbin Cai and Huaqiang Fan and Dazhong Ding and Yongqiang Zhang and Wei Wang",

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T2 - Z -alkenes via visible light promoted photocatalytic e → Z isomerization under metal-free conditions

AU - Cai, Wenbin

AU - Fan, Huaqiang

AU - Ding, Dazhong

AU - Zhang, Yongqiang

AU - Wang, Wei

PY - 2017

Y1 - 2017

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AB - A green approach for the synthesis of thermodynamically less stable Z-alkenes has been presented through the exploration of visible light promoted photocatalytic E-to-Z isomerization. This protocol features metal-free conditions, which is operationally simple, remarkably clean, and allows the synthesis of both electron-rich and electron-deficient Z-alkenes with diverse functional groups.

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Synthesis of: Z -alkenes via visible light promoted photocatalytic e → Z isomerization under metal-free conditions

Abstract

ASJC Scopus subject areas

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