Synthesis of polypropylene-poly(meth)acrylate block copolymers using metallocene catalyzed processes and subsequent atom transfer radical polymerization

Krzysztof Matyjaszewski; Jocelyn Saget; Jeffrey Pyun; Martin Schlögl; Bernhard Rieger

doi:10.1081/MA-120013570

Synthesis of polypropylene-poly(meth)acrylate block copolymers using metallocene catalyzed processes and subsequent atom transfer radical polymerization

Krzysztof Matyjaszewski
, Jocelyn Saget
, Jeffrey Pyun
, Martin Schlögl
, Bernhard Rieger

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The synthesis of block copolymers containing low molar mass polypropylene and poly(meth)acrylates is reported. Vinyl-terminated polypropylene (M_nSEC = 3,100; M_w/M_n = 1.45) was used to prepare a macroinitiator for atom transfer radical polymerization (ATRP) via hydrosilation with 1-(2-bromoisobutyryloxy)propyl-tetramethyldisiloxane. Polar segments were then incorporated to polypropylene by chain extension using either methyl methacrylate, or n-butyl acrylate. While blocking efficiency was limited in this system, well-defined PP-b-PMMA (M_n = 22,220; M_w/M_n = 1.14) was obtained by extraction of unreacted polypropylene with diethyl ether.

Original language	English (US)
Pages (from-to)	901-913
Number of pages	13
Journal	Journal of Macromolecular Science - Pure and Applied Chemistry
Volume	39 A
Issue number	9
DOIs	https://doi.org/10.1081/MA-120013570
State	Published - Sep 2002
Externally published	Yes

Keywords

Atom transfer radical polymerization (ATRP)
Polyolefin containing polar segments
Polypropylene copolymers

ASJC Scopus subject areas

Ceramics and Composites
General Chemistry
Polymers and Plastics
Materials Chemistry

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10.1081/MA-120013570

Cite this

Synthesis of polypropylene-poly(meth)acrylate block copolymers using metallocene catalyzed processes and subsequent atom transfer radical polymerization. / Matyjaszewski, Krzysztof; Saget, Jocelyn; Pyun, Jeffrey et al.
In: Journal of Macromolecular Science - Pure and Applied Chemistry, Vol. 39 A, No. 9, 09.2002, p. 901-913.

Research output: Contribution to journal › Article › peer-review

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title = "Synthesis of polypropylene-poly(meth)acrylate block copolymers using metallocene catalyzed processes and subsequent atom transfer radical polymerization",

abstract = "The synthesis of block copolymers containing low molar mass polypropylene and poly(meth)acrylates is reported. Vinyl-terminated polypropylene (MnSEC = 3,100; Mw/Mn = 1.45) was used to prepare a macroinitiator for atom transfer radical polymerization (ATRP) via hydrosilation with 1-(2-bromoisobutyryloxy)propyl-tetramethyldisiloxane. Polar segments were then incorporated to polypropylene by chain extension using either methyl methacrylate, or n-butyl acrylate. While blocking efficiency was limited in this system, well-defined PP-b-PMMA (Mn = 22,220; Mw/Mn = 1.14) was obtained by extraction of unreacted polypropylene with diethyl ether.",

keywords = "Atom transfer radical polymerization (ATRP), Polyolefin containing polar segments, Polypropylene copolymers",

author = "Krzysztof Matyjaszewski and Jocelyn Saget and Jeffrey Pyun and Martin Schl{\"o}gl and Bernhard Rieger",

note = "Funding Information: The National Science Foundation (DMR-0090409) and Controlled Radical Polymerization Consoritium are greatfully acknowledged for funding of the research. JP acknowledges Dr. John and Nancy Harrison for funding of the Legacy Fellowship at CMU.",

year = "2002",

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language = "English (US)",

volume = "39 A",

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T1 - Synthesis of polypropylene-poly(meth)acrylate block copolymers using metallocene catalyzed processes and subsequent atom transfer radical polymerization

AU - Matyjaszewski, Krzysztof

AU - Saget, Jocelyn

AU - Pyun, Jeffrey

AU - Schlögl, Martin

AU - Rieger, Bernhard

N1 - Funding Information: The National Science Foundation (DMR-0090409) and Controlled Radical Polymerization Consoritium are greatfully acknowledged for funding of the research. JP acknowledges Dr. John and Nancy Harrison for funding of the Legacy Fellowship at CMU.

PY - 2002/9

Y1 - 2002/9

N2 - The synthesis of block copolymers containing low molar mass polypropylene and poly(meth)acrylates is reported. Vinyl-terminated polypropylene (MnSEC = 3,100; Mw/Mn = 1.45) was used to prepare a macroinitiator for atom transfer radical polymerization (ATRP) via hydrosilation with 1-(2-bromoisobutyryloxy)propyl-tetramethyldisiloxane. Polar segments were then incorporated to polypropylene by chain extension using either methyl methacrylate, or n-butyl acrylate. While blocking efficiency was limited in this system, well-defined PP-b-PMMA (Mn = 22,220; Mw/Mn = 1.14) was obtained by extraction of unreacted polypropylene with diethyl ether.

AB - The synthesis of block copolymers containing low molar mass polypropylene and poly(meth)acrylates is reported. Vinyl-terminated polypropylene (MnSEC = 3,100; Mw/Mn = 1.45) was used to prepare a macroinitiator for atom transfer radical polymerization (ATRP) via hydrosilation with 1-(2-bromoisobutyryloxy)propyl-tetramethyldisiloxane. Polar segments were then incorporated to polypropylene by chain extension using either methyl methacrylate, or n-butyl acrylate. While blocking efficiency was limited in this system, well-defined PP-b-PMMA (Mn = 22,220; Mw/Mn = 1.14) was obtained by extraction of unreacted polypropylene with diethyl ether.

KW - Atom transfer radical polymerization (ATRP)

KW - Polyolefin containing polar segments

KW - Polypropylene copolymers

UR - https://www.scopus.com/pages/publications/0036745040

UR - https://www.scopus.com/pages/publications/0036745040#tab=citedBy

U2 - 10.1081/MA-120013570

DO - 10.1081/MA-120013570

M3 - Article

AN - SCOPUS:0036745040

SN - 1060-1325

VL - 39 A

SP - 901

EP - 913

JO - Journal of Macromolecular Science - Pure and Applied Chemistry

JF - Journal of Macromolecular Science - Pure and Applied Chemistry

IS - 9

ER -

Synthesis of polypropylene-poly(meth)acrylate block copolymers using metallocene catalyzed processes and subsequent atom transfer radical polymerization

Abstract

Keywords

ASJC Scopus subject areas

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