Synthesis of optically active chiral shell dendrons

Denise M. Junge; Dominic V. McGrath

doi:10.1016/S0040-4039(98)00135-X

Synthesis of optically active chiral shell dendrons

Denise M. Junge, Dominic V. McGrath

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

We present the preparation of a series of chiral dendrons, in which chiral subunits are placed in individual generational shells at increasing distances from the focal point, by a combination of convergent and divergent dendrimer synthesis methods. Analysis of chiroptical data suggests that these dendrons do not possess conformational order in solution.

Original language	English (US)
Pages (from-to)	1701-1704
Number of pages	4
Journal	Tetrahedron Letters
Volume	39
Issue number	13
DOIs	https://doi.org/10.1016/S0040-4039(98)00135-X
State	Published - Mar 26 1998
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(98)00135-X

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title = "Synthesis of optically active chiral shell dendrons",

abstract = "We present the preparation of a series of chiral dendrons, in which chiral subunits are placed in individual generational shells at increasing distances from the focal point, by a combination of convergent and divergent dendrimer synthesis methods. Analysis of chiroptical data suggests that these dendrons do not possess conformational order in solution.",

author = "Junge, \{Denise M.\} and McGrath, \{Dominic V.\}",

note = "Funding Information: Acknowledgment. We are grateful to the National Science Foundation (DMR-9702123) and the Petroleum Research Fund (29720-G7), administered by the American Chemical Society, for support of this research. We thank Mu-Jen Wu for assistance in the preparation of compounds 6 and 12.",

year = "1998",

month = mar,

day = "26",

doi = "10.1016/S0040-4039(98)00135-X",

language = "English (US)",

volume = "39",

pages = "1701--1704",

journal = "Tetrahedron Letters",

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publisher = "Elsevier Ltd",

number = "13",

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TY - JOUR

T1 - Synthesis of optically active chiral shell dendrons

AU - Junge, Denise M.

AU - McGrath, Dominic V.

N1 - Funding Information: Acknowledgment. We are grateful to the National Science Foundation (DMR-9702123) and the Petroleum Research Fund (29720-G7), administered by the American Chemical Society, for support of this research. We thank Mu-Jen Wu for assistance in the preparation of compounds 6 and 12.

PY - 1998/3/26

Y1 - 1998/3/26

N2 - We present the preparation of a series of chiral dendrons, in which chiral subunits are placed in individual generational shells at increasing distances from the focal point, by a combination of convergent and divergent dendrimer synthesis methods. Analysis of chiroptical data suggests that these dendrons do not possess conformational order in solution.

AB - We present the preparation of a series of chiral dendrons, in which chiral subunits are placed in individual generational shells at increasing distances from the focal point, by a combination of convergent and divergent dendrimer synthesis methods. Analysis of chiroptical data suggests that these dendrons do not possess conformational order in solution.

UR - https://www.scopus.com/pages/publications/0032568271

UR - https://www.scopus.com/inward/citedby.url?scp=0032568271&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(98)00135-X

DO - 10.1016/S0040-4039(98)00135-X

M3 - Article

AN - SCOPUS:0032568271

SN - 0040-4039

VL - 39

SP - 1701

EP - 1704

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 13

ER -

Synthesis of optically active chiral shell dendrons

Abstract

ASJC Scopus subject areas

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