Synthesis and properties of semiconducting aromatic polyquinonediimines

A. Everaerts; Sue Roberts; H. K. Hall

doi:10.1002/pola.1986.080240727

Synthesis and properties of semiconducting aromatic polyquinonediimines

A. Everaerts, Sue Roberts, H. K. Hall

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Abstract

A new class of poly‐conjugated polymers has been obtained by condensation of anthraquinones with aromatic diamines in polyphosphoric acid. The polymers are black, intractable powders. Toward obtaining tractable materials, the effect of monomer structure on polymer tractability has been studied. Copolymerizations were also carried out to “soften” these materials. Electrical conductivities in the semiconducting range, 10⁻⁴‐ 10⁻⁸ (ohm cm)⁻¹ were observed. Doping with iodine showed small increases.

Original language	English (US)
Pages (from-to)	1703-1716
Number of pages	14
Journal	Journal of Polymer Science Part A: Polymer Chemistry
Volume	24
Issue number	7
DOIs	https://doi.org/10.1002/pola.1986.080240727
State	Published - Jul 1986
Externally published	Yes

ASJC Scopus subject areas

Polymers and Plastics
Organic Chemistry
Materials Chemistry

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abstract = "A new class of poly‐conjugated polymers has been obtained by condensation of anthraquinones with aromatic diamines in polyphosphoric acid. The polymers are black, intractable powders. Toward obtaining tractable materials, the effect of monomer structure on polymer tractability has been studied. Copolymerizations were also carried out to “soften” these materials. Electrical conductivities in the semiconducting range, 10−4‐ 10−8 (ohm cm)−1 were observed. Doping with iodine showed small increases.",

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year = "1986",

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AB - A new class of poly‐conjugated polymers has been obtained by condensation of anthraquinones with aromatic diamines in polyphosphoric acid. The polymers are black, intractable powders. Toward obtaining tractable materials, the effect of monomer structure on polymer tractability has been studied. Copolymerizations were also carried out to “soften” these materials. Electrical conductivities in the semiconducting range, 10−4‐ 10−8 (ohm cm)−1 were observed. Doping with iodine showed small increases.

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JF - Journal of Polymer Science Part A: Polymer Chemistry

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Synthesis and properties of semiconducting aromatic polyquinonediimines

Abstract

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