Surface enhanced Raman scattering at Ag electrodes in non-aqueous pyridine solutions

Jeanne E. Pemberton

doi:10.1016/0009-2614(85)80036-1

Surface enhanced Raman scattering at Ag electrodes in non-aqueous pyridine solutions

Jeanne E. Pemberton

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The surface enhanced Raman scattering (SERS) of interfacial pyridine and Br^- species at Ag electrodes from neat pyridine solutions containing tetra-n-butylammonium bromide is presented. The potential dependence of the SERS peak frequencies, bandwidths, and relative intensities is reported and interpreted in terms of pyridine reorientation in the double layer. A band at 221 cm^-1 is observed at certain potentials and is assigned to the AgN stretch for Ag surface pyridine species.

Original language	English (US)
Pages (from-to)	321-327
Number of pages	7
Journal	Chemical Physics Letters
Volume	115
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(85)80036-1
State	Published - Apr 5 1985

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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@article{f7975620c53145329b4ea25ba38c9efb,

title = "Surface enhanced Raman scattering at Ag electrodes in non-aqueous pyridine solutions",

abstract = "The surface enhanced Raman scattering (SERS) of interfacial pyridine and Br- species at Ag electrodes from neat pyridine solutions containing tetra-n-butylammonium bromide is presented. The potential dependence of the SERS peak frequencies, bandwidths, and relative intensities is reported and interpreted in terms of pyridine reorientation in the double layer. A band at 221 cm-1 is observed at certain potentials and is assigned to the AgN stretch for Ag surface pyridine species.",

author = "Pemberton, \{Jeanne E.\}",

note = "Funding Information: The author gratefully acknowIedges the financial support of this research by DuPont in the form of a DuPont Young Faculty Development Grant, the National Science Foundation (CHE-8309454). Research Corporation, and the Petroleum Research Fund, administered by the American Chemical Society.",

year = "1985",

month = apr,

day = "5",

doi = "10.1016/0009-2614(85)80036-1",

language = "English (US)",

volume = "115",

pages = "321--327",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "3",

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TY - JOUR

T1 - Surface enhanced Raman scattering at Ag electrodes in non-aqueous pyridine solutions

AU - Pemberton, Jeanne E.

N1 - Funding Information: The author gratefully acknowIedges the financial support of this research by DuPont in the form of a DuPont Young Faculty Development Grant, the National Science Foundation (CHE-8309454). Research Corporation, and the Petroleum Research Fund, administered by the American Chemical Society.

PY - 1985/4/5

Y1 - 1985/4/5

N2 - The surface enhanced Raman scattering (SERS) of interfacial pyridine and Br- species at Ag electrodes from neat pyridine solutions containing tetra-n-butylammonium bromide is presented. The potential dependence of the SERS peak frequencies, bandwidths, and relative intensities is reported and interpreted in terms of pyridine reorientation in the double layer. A band at 221 cm-1 is observed at certain potentials and is assigned to the AgN stretch for Ag surface pyridine species.

AB - The surface enhanced Raman scattering (SERS) of interfacial pyridine and Br- species at Ag electrodes from neat pyridine solutions containing tetra-n-butylammonium bromide is presented. The potential dependence of the SERS peak frequencies, bandwidths, and relative intensities is reported and interpreted in terms of pyridine reorientation in the double layer. A band at 221 cm-1 is observed at certain potentials and is assigned to the AgN stretch for Ag surface pyridine species.

UR - https://www.scopus.com/pages/publications/0001528750

UR - https://www.scopus.com/pages/publications/0001528750#tab=citedBy

U2 - 10.1016/0009-2614(85)80036-1

DO - 10.1016/0009-2614(85)80036-1

M3 - Article

AN - SCOPUS:0001528750

SN - 0009-2614

VL - 115

SP - 321

EP - 327

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3

ER -

Surface enhanced Raman scattering at Ag electrodes in non-aqueous pyridine solutions

Abstract

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