TY - JOUR
T1 - Surface enhanced Raman scattering at Ag electrodes in non-aqueous pyridine solutions
AU - Pemberton, Jeanne E.
N1 - Funding Information:
The author gratefully acknowIedges the financial support of this research by DuPont in the form of a DuPont Young Faculty Development Grant, the National Science Foundation (CHE-8309454). Research Corporation, and the Petroleum Research Fund, administered by the American Chemical Society.
PY - 1985/4/5
Y1 - 1985/4/5
N2 - The surface enhanced Raman scattering (SERS) of interfacial pyridine and Br- species at Ag electrodes from neat pyridine solutions containing tetra-n-butylammonium bromide is presented. The potential dependence of the SERS peak frequencies, bandwidths, and relative intensities is reported and interpreted in terms of pyridine reorientation in the double layer. A band at 221 cm-1 is observed at certain potentials and is assigned to the AgN stretch for Ag surface pyridine species.
AB - The surface enhanced Raman scattering (SERS) of interfacial pyridine and Br- species at Ag electrodes from neat pyridine solutions containing tetra-n-butylammonium bromide is presented. The potential dependence of the SERS peak frequencies, bandwidths, and relative intensities is reported and interpreted in terms of pyridine reorientation in the double layer. A band at 221 cm-1 is observed at certain potentials and is assigned to the AgN stretch for Ag surface pyridine species.
UR - https://www.scopus.com/pages/publications/0001528750
UR - https://www.scopus.com/inward/citedby.url?scp=0001528750&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(85)80036-1
DO - 10.1016/0009-2614(85)80036-1
M3 - Article
AN - SCOPUS:0001528750
SN - 0009-2614
VL - 115
SP - 321
EP - 327
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 3
ER -