Supramolecular Assembly of Complementary Cyanine Salt J-Aggregates

Zhong'An Li; Sukrit Mukhopadhyay; Sei Hum Jang; Jean Luc Brédas; Alex K.Y. Jen

doi:10.1021/jacs.5b08072

Supramolecular Assembly of Complementary Cyanine Salt J-Aggregates

Zhong'An Li, Sukrit Mukhopadhyay, Sei Hum Jang, Jean Luc Brédas, Alex K.Y. Jen

Research output: Contribution to journal › Article › peer-review

54 Scopus citations

Abstract

An understanding of structure-property relationships in cyanine dyes is critical for their design and application. Anionic and cationic cyanines can be organized into complementary cyanine salts, offering potential building blocks to modulate their intra/intermolecular interactions in the solid state. Here, we demonstrate how the structures of these complementary salts can be tuned to achieve highly ordered J-type supramolecular aggregate structures of heptamethine dyes in crystalline solids.

Original language	English (US)
Pages (from-to)	11920-11923
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	37
DOIs	https://doi.org/10.1021/jacs.5b08072
State	Published - Sep 23 2015
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/jacs.5b08072

Cite this

@article{0f0749e31d5645c28c7a9af9077eb5ee,

title = "Supramolecular Assembly of Complementary Cyanine Salt J-Aggregates",

abstract = "An understanding of structure-property relationships in cyanine dyes is critical for their design and application. Anionic and cationic cyanines can be organized into complementary cyanine salts, offering potential building blocks to modulate their intra/intermolecular interactions in the solid state. Here, we demonstrate how the structures of these complementary salts can be tuned to achieve highly ordered J-type supramolecular aggregate structures of heptamethine dyes in crystalline solids.",

author = "Zhong'An Li and Sukrit Mukhopadhyay and Jang, {Sei Hum} and Br{\'e}das, {Jean Luc} and Jen, {Alex K.Y.}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

month = sep,

day = "23",

doi = "10.1021/jacs.5b08072",

language = "English (US)",

volume = "137",

pages = "11920--11923",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "37",

}

TY - JOUR

T1 - Supramolecular Assembly of Complementary Cyanine Salt J-Aggregates

AU - Li, Zhong'An

AU - Mukhopadhyay, Sukrit

AU - Jang, Sei Hum

AU - Brédas, Jean Luc

AU - Jen, Alex K.Y.

PY - 2015/9/23

Y1 - 2015/9/23

N2 - An understanding of structure-property relationships in cyanine dyes is critical for their design and application. Anionic and cationic cyanines can be organized into complementary cyanine salts, offering potential building blocks to modulate their intra/intermolecular interactions in the solid state. Here, we demonstrate how the structures of these complementary salts can be tuned to achieve highly ordered J-type supramolecular aggregate structures of heptamethine dyes in crystalline solids.

AB - An understanding of structure-property relationships in cyanine dyes is critical for their design and application. Anionic and cationic cyanines can be organized into complementary cyanine salts, offering potential building blocks to modulate their intra/intermolecular interactions in the solid state. Here, we demonstrate how the structures of these complementary salts can be tuned to achieve highly ordered J-type supramolecular aggregate structures of heptamethine dyes in crystalline solids.

UR - http://www.scopus.com/inward/record.url?scp=84942279236&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84942279236&partnerID=8YFLogxK

U2 - 10.1021/jacs.5b08072

DO - 10.1021/jacs.5b08072

M3 - Article

AN - SCOPUS:84942279236

SN - 0002-7863

VL - 137

SP - 11920

EP - 11923

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 37

ER -

Supramolecular Assembly of Complementary Cyanine Salt J-Aggregates

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this