1H and 13C NMR signal assignments of a novel Baeyer-Villiger originated diterpene lactone

Henriete S. Vieira; Jacqueline A. Takahashi; A. A.Leslie Gunatilaka; Maria Amélia D. Boaventura

doi:10.1002/mrc.1738

¹H and ¹³C NMR signal assignments of a novel Baeyer-Villiger originated diterpene lactone

Henriete S. Vieira
, Jacqueline A. Takahashi
, A. A.Leslie Gunatilaka
, Maria Amélia D. Boaventura

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A highly rearranged novel dilactone was the single product isolated from Baeyer-Villiger oxidation of a norketone prepared from grandiflorenic acid, a natural kaurane diterpene. The complete ¹H and ¹³C NMR assignment is presented for this novel compound that showed discrete in vitro antibacterial activity.

Original language	English (US)
Pages (from-to)	146-150
Number of pages	5
Journal	Magnetic Resonance in Chemistry
Volume	44
Issue number	2
DOIs	https://doi.org/10.1002/mrc.1738
State	Published - Feb 2006

Keywords

1D NMR
2D NMR
Baeyer-Villiger oxidation
Kaurane diterpene lactones

ASJC Scopus subject areas

General Chemistry
General Materials Science

Access to Document

10.1002/mrc.1738

Cite this

@article{dbd6369631ab48c29c07a767e92c6d0b,

title = "1H and 13C NMR signal assignments of a novel Baeyer-Villiger originated diterpene lactone",

abstract = "A highly rearranged novel dilactone was the single product isolated from Baeyer-Villiger oxidation of a norketone prepared from grandiflorenic acid, a natural kaurane diterpene. The complete 1H and 13C NMR assignment is presented for this novel compound that showed discrete in vitro antibacterial activity.",

keywords = "1D NMR, 2D NMR, Baeyer-Villiger oxidation, Kaurane diterpene lactones",

author = "Vieira, \{Henriete S.\} and Takahashi, \{Jacqueline A.\} and Gunatilaka, \{A. A.Leslie\} and Boaventura, \{Maria Am{\'e}lia D.\}",

year = "2006",

month = feb,

doi = "10.1002/mrc.1738",

language = "English (US)",

volume = "44",

pages = "146--150",

journal = "Magnetic Resonance in Chemistry",

issn = "0749-1581",

publisher = "John Wiley and Sons Ltd",

number = "2",

}

TY - JOUR

T1 - 1H and 13C NMR signal assignments of a novel Baeyer-Villiger originated diterpene lactone

AU - Vieira, Henriete S.

AU - Takahashi, Jacqueline A.

AU - Gunatilaka, A. A.Leslie

AU - Boaventura, Maria Amélia D.

PY - 2006/2

Y1 - 2006/2

N2 - A highly rearranged novel dilactone was the single product isolated from Baeyer-Villiger oxidation of a norketone prepared from grandiflorenic acid, a natural kaurane diterpene. The complete 1H and 13C NMR assignment is presented for this novel compound that showed discrete in vitro antibacterial activity.

AB - A highly rearranged novel dilactone was the single product isolated from Baeyer-Villiger oxidation of a norketone prepared from grandiflorenic acid, a natural kaurane diterpene. The complete 1H and 13C NMR assignment is presented for this novel compound that showed discrete in vitro antibacterial activity.

KW - 1D NMR

KW - 2D NMR

KW - Baeyer-Villiger oxidation

KW - Kaurane diterpene lactones

UR - https://www.scopus.com/pages/publications/31644451643

UR - https://www.scopus.com/pages/publications/31644451643#tab=citedBy

U2 - 10.1002/mrc.1738

DO - 10.1002/mrc.1738

M3 - Article

C2 - 16358289

AN - SCOPUS:31644451643

SN - 0749-1581

VL - 44

SP - 146

EP - 150

JO - Magnetic Resonance in Chemistry

JF - Magnetic Resonance in Chemistry

IS - 2

ER -