Stereochemically defined C-substituted glutamic acids and their derivatives. 1. An efficient asymmetric synthesis of (2S,3S)-3-methyl- and - 3-trifluoromethylpyroglutamic acids

Keyphrases

• Methyl 100%
• Glutamic Acid 100%
• Asymmetric Synthesis 100%
• Addition Reaction 50%
• Glycine 50%
• Ni(II) Complex 50%
• Racemic 50%
• Schiff Base 50%
• Chiral Auxiliary 50%
• Ammonium Hydroxide 50%
• Pyroglutamic Acid 50%
• Aminobenzophenone 50%
• Michael Addition Reaction 50%
• Ethyl 50%
• Stereochemical Hypothesis 50%
• Kinetic Control 50%
• Thiol-Michael Addition 50%
• Methyl Crotonate 50%
• Glutamic Acid Derivatives 50%
• Addition Products 50%
• Stereochemical Outcome 50%

Chemistry

• Addition Reaction 100%
• Asymmetric Synthesis 100%
• Ethyl 100%
• Glutamic Acid 100%
• Chemical Kinetics Characteristics 50%
• Benzophenone 50%
• Chiral Auxiliary 50%
• Michael Addition 50%
• Crotonate 50%
• Glutamic Acid Derivative 50%
• Imine 50%
• Amino Acid 50%