TY - JOUR
T1 - Standard Electromotive Force of Silver-Silver Chloride Electrode and Related Thermodynamic Quantities in tert-Butyl Alcohol-Water Mixtures (2, 6, and 8 Wt %) between 5-45°
AU - Roy, Rabindra N.
AU - Vernon, William
AU - Bothwell, Alfred
AU - Gibbons, James
PY - 1972/1/1
Y1 - 1972/1/1
N2 - The electromotive force measurements of the cell Pt, H2 (1 atm) | HCl (m) in H2O | | HCl (m), ButOH (x), H2O (y) | AgCl, Ag at nine temperatures in the range 5-45° were used to derive the standard potential of the cell, the activity coefficient of HCI for molalities in the range 0.002-0.1, and the thermodynamic functions, δG°, δH°, and δS0, for the transfer of HCI from water to the respective ferf-butyl alcohol-water mixtures. The standard potential was calculated by a theoretically justified polynomial curve-fitting program and varied with temperature, f, °, according to the equations The molality of the acid ranged from 0.005-0.2 mol kg-1.
AB - The electromotive force measurements of the cell Pt, H2 (1 atm) | HCl (m) in H2O | | HCl (m), ButOH (x), H2O (y) | AgCl, Ag at nine temperatures in the range 5-45° were used to derive the standard potential of the cell, the activity coefficient of HCI for molalities in the range 0.002-0.1, and the thermodynamic functions, δG°, δH°, and δS0, for the transfer of HCI from water to the respective ferf-butyl alcohol-water mixtures. The standard potential was calculated by a theoretically justified polynomial curve-fitting program and varied with temperature, f, °, according to the equations The molality of the acid ranged from 0.005-0.2 mol kg-1.
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U2 - 10.1021/je60052a042
DO - 10.1021/je60052a042
M3 - Article
AN - SCOPUS:33947088469
SN - 0021-9568
VL - 17
SP - 79
EP - 81
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 1
ER -