Stability of model VPO catalysts for maleic anhydride synthesis

T. P. Moser; G. L. Schrader

doi:10.1016/0021-9517(87)90340-X

Stability of model VPO catalysts for maleic anhydride synthesis

T. P. Moser
, G. L. Schrader

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

The stability of β-VOPO₄ and (VO)₂P₂O₇ under conditions of n-butane and 1-butene oxidation was investigated using the complementary techniques of in situ laser Raman spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Both β-VOPO₄ and (VO)₂P₂O₇ demonstrated bulk structural integrity during n-butane oxidation. The relatively greater reducing capacity of 1-butene, however, induced a transformation of β-VOPO₄ to (VO)₂P₂O₇. The presence of V(V) and V(IV) in used β-VOPO₄ and (VO)₂P₂O₇ was detected by X-ray photoelectron spectroscopy for both hydrocarbon oxidation conditions.

Original language	English (US)
Pages (from-to)	99-108
Number of pages	10
Journal	Journal of Catalysis
Volume	104
Issue number	1
DOIs	https://doi.org/10.1016/0021-9517(87)90340-X
State	Published - Mar 1987
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

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10.1016/0021-9517(87)90340-X

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title = "Stability of model VPO catalysts for maleic anhydride synthesis",

abstract = "The stability of β-VOPO4 and (VO)2P2O7 under conditions of n-butane and 1-butene oxidation was investigated using the complementary techniques of in situ laser Raman spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Both β-VOPO4 and (VO)2P2O7 demonstrated bulk structural integrity during n-butane oxidation. The relatively greater reducing capacity of 1-butene, however, induced a transformation of β-VOPO4 to (VO)2P2O7. The presence of V(V) and V(IV) in used β-VOPO4 and (VO)2P2O7 was detected by X-ray photoelectron spectroscopy for both hydrocarbon oxidation conditions.",

author = "Moser, \{T. P.\} and Schrader, \{G. L.\}",

note = "Funding Information: This work was conductedt hrought he Ames Laboratory which is operatedf or the U.S. Departmento f Energy by Iowa State University under Contract W-7405ENG-82. The X-ray photoelectrons pectroscopy work by James W. Anderegg is gratefully acknowl-",

year = "1987",

month = mar,

doi = "10.1016/0021-9517(87)90340-X",

language = "English (US)",

volume = "104",

pages = "99--108",

journal = "Journal of Catalysis",

issn = "0021-9517",

publisher = "Academic Press Inc.",

number = "1",

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TY - JOUR

T1 - Stability of model VPO catalysts for maleic anhydride synthesis

AU - Moser, T. P.

AU - Schrader, G. L.

N1 - Funding Information: This work was conductedt hrought he Ames Laboratory which is operatedf or the U.S. Departmento f Energy by Iowa State University under Contract W-7405ENG-82. The X-ray photoelectrons pectroscopy work by James W. Anderegg is gratefully acknowl-

PY - 1987/3

Y1 - 1987/3

N2 - The stability of β-VOPO4 and (VO)2P2O7 under conditions of n-butane and 1-butene oxidation was investigated using the complementary techniques of in situ laser Raman spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Both β-VOPO4 and (VO)2P2O7 demonstrated bulk structural integrity during n-butane oxidation. The relatively greater reducing capacity of 1-butene, however, induced a transformation of β-VOPO4 to (VO)2P2O7. The presence of V(V) and V(IV) in used β-VOPO4 and (VO)2P2O7 was detected by X-ray photoelectron spectroscopy for both hydrocarbon oxidation conditions.

AB - The stability of β-VOPO4 and (VO)2P2O7 under conditions of n-butane and 1-butene oxidation was investigated using the complementary techniques of in situ laser Raman spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Both β-VOPO4 and (VO)2P2O7 demonstrated bulk structural integrity during n-butane oxidation. The relatively greater reducing capacity of 1-butene, however, induced a transformation of β-VOPO4 to (VO)2P2O7. The presence of V(V) and V(IV) in used β-VOPO4 and (VO)2P2O7 was detected by X-ray photoelectron spectroscopy for both hydrocarbon oxidation conditions.

UR - https://www.scopus.com/pages/publications/0010689121

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U2 - 10.1016/0021-9517(87)90340-X

DO - 10.1016/0021-9517(87)90340-X

M3 - Article

AN - SCOPUS:0010689121

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VL - 104

SP - 99

EP - 108

JO - Journal of Catalysis

JF - Journal of Catalysis

IS - 1

ER -

Stability of model VPO catalysts for maleic anhydride synthesis

Abstract

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