Solvated electrons in very small clusters of polar molecules: (HF)3-

M. Gutowski; M. Gutowski; C. S. Hall; L. Adamowicz; J. H. Hendricks; H. L. de Clercq; S. A. Lyapustina; J. M. Nilles; S. J. Xu; K. H. Bowen

doi:10.1103/PhysRevLett.88.143001

Solvated electrons in very small clusters of polar molecules: (HF)₃^-

M. Gutowski, M. Gutowski, C. S. Hall, L. Adamowicz, J. H. Hendricks, H. L. de Clercq, S. A. Lyapustina, J. M. Nilles, S. J. Xu, K. H. Bowen

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66 Scopus citations

Abstract

The coexistence of dbe and se in as small a cluster as (HF)₃^- is illustrated. The stability of these anions with respect to the neutral cluster results not only from the excess electron binding energy but also from favorable entropic effects, which reflect the greater "floppiness" of the anionic structures.

Original language	English (US)
Article number	143001
Pages (from-to)	143001/1-143001/4
Journal	Physical review letters
Volume	88
Issue number	14
DOIs	https://doi.org/10.1103/PhysRevLett.88.143001
State	Published - Apr 8 2002

ASJC Scopus subject areas

General Physics and Astronomy

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10.1103/PhysRevLett.88.143001

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abstract = "The coexistence of dbe and se in as small a cluster as (HF)3- is illustrated. The stability of these anions with respect to the neutral cluster results not only from the excess electron binding energy but also from favorable entropic effects, which reflect the greater {"}floppiness{"} of the anionic structures.",

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T2 - (HF)3-

AU - Gutowski, M.

AU - Hall, C. S.

AU - Adamowicz, L.

AU - Hendricks, J. H.

AU - de Clercq, H. L.

AU - Lyapustina, S. A.

AU - Nilles, J. M.

AU - Xu, S. J.

AU - Bowen, K. H.

PY - 2002/4/8

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N2 - The coexistence of dbe and se in as small a cluster as (HF)3- is illustrated. The stability of these anions with respect to the neutral cluster results not only from the excess electron binding energy but also from favorable entropic effects, which reflect the greater "floppiness" of the anionic structures.

AB - The coexistence of dbe and se in as small a cluster as (HF)3- is illustrated. The stability of these anions with respect to the neutral cluster results not only from the excess electron binding energy but also from favorable entropic effects, which reflect the greater "floppiness" of the anionic structures.

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Solvated electrons in very small clusters of polar molecules: (HF)₃^-

Abstract

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