Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection

M. E. Van der Boom; A. G. Richter; J. E. Malinsky; P. A. Lee; N. R. Armstrong; P. Dutta; T. J. Marks

doi:10.1021/cm000746w

Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection

M. E. Van der Boom, A. G. Richter, J. E. Malinsky, P. A. Lee, N. R. Armstrong, P. Dutta, T. J. Marks

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Protection-deprotection of silyl-derivatized surface hydroxyl groups represents a new, "one-pot" strategy for the layer-by-layer construction of polar, covalently interlinked electrooptic molecular superlattices. These, siloxane-based multilayer structures are shown to be smooth, adherent, and structurally regular and to exhibit excellent electrooptic/nonlinear optic responses with χ⁽²⁾_zzz∼220 pm/V and r₃₃∼80 pm/V without electric field poling. This all "wet-chemical self-assembly approach should be readily amenable to automation.

Original language	English (US)
Pages (from-to)	15-17
Number of pages	3
Journal	Chemistry of Materials
Volume	13
Issue number	1
DOIs	https://doi.org/10.1021/cm000746w
State	Published - 2001

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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title = "Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection",

abstract = "Protection-deprotection of silyl-derivatized surface hydroxyl groups represents a new, {"}one-pot{"} strategy for the layer-by-layer construction of polar, covalently interlinked electrooptic molecular superlattices. These, siloxane-based multilayer structures are shown to be smooth, adherent, and structurally regular and to exhibit excellent electrooptic/nonlinear optic responses with χ(2)zzz∼220 pm/V and r33∼80 pm/V without electric field poling. This all {"}wet-chemical self-assembly approach should be readily amenable to automation.",

author = "{Van der Boom}, {M. E.} and Richter, {A. G.} and Malinsky, {J. E.} and Lee, {P. A.} and Armstrong, {N. R.} and P. Dutta and Marks, {T. J.}",

year = "2001",

doi = "10.1021/cm000746w",

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AU - Van der Boom, M. E.

AU - Richter, A. G.

AU - Malinsky, J. E.

AU - Lee, P. A.

AU - Armstrong, N. R.

AU - Dutta, P.

AU - Marks, T. J.

PY - 2001

Y1 - 2001

N2 - Protection-deprotection of silyl-derivatized surface hydroxyl groups represents a new, "one-pot" strategy for the layer-by-layer construction of polar, covalently interlinked electrooptic molecular superlattices. These, siloxane-based multilayer structures are shown to be smooth, adherent, and structurally regular and to exhibit excellent electrooptic/nonlinear optic responses with χ(2)zzz∼220 pm/V and r33∼80 pm/V without electric field poling. This all "wet-chemical self-assembly approach should be readily amenable to automation.

AB - Protection-deprotection of silyl-derivatized surface hydroxyl groups represents a new, "one-pot" strategy for the layer-by-layer construction of polar, covalently interlinked electrooptic molecular superlattices. These, siloxane-based multilayer structures are shown to be smooth, adherent, and structurally regular and to exhibit excellent electrooptic/nonlinear optic responses with χ(2)zzz∼220 pm/V and r33∼80 pm/V without electric field poling. This all "wet-chemical self-assembly approach should be readily amenable to automation.

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Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection

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