Selective oxidation over structured multicomponent molybdate catalysts

Joe Y. Zou; Glenn L. Schrader

doi:10.1016/S0167-2991(08)63394-7

Selective oxidation over structured multicomponent molybdate catalysts

Joe Y. Zou, Glenn L. Schrader

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

NiMoO₄-MoO₃ catalysts prepared by reactive sputtering were evaluated for the conversion of 1-butene to furan and maleic anhydride. As for precipitated catalysts, individual phases of NiMoO₄ or MoO₃ yielded very little of these products; however, thin films (150-300 A) of NiMoO₄ on M0O3 (010) surfaces were highly active and selective. The sputtering technique has significant advantages for preparation and characterization of multicomponent catalysts compared to precipitation or impregnation routes.

Original language	English (US)
Pages (from-to)	19-30
Number of pages	12
Journal	Studies in Surface Science and Catalysis
Volume	82
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(08)63394-7
State	Published - Jan 1 1994
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/S0167-2991(08)63394-7

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title = "Selective oxidation over structured multicomponent molybdate catalysts",

abstract = "NiMoO4-MoO3 catalysts prepared by reactive sputtering were evaluated for the conversion of 1-butene to furan and maleic anhydride. As for precipitated catalysts, individual phases of NiMoO4 or MoO3 yielded very little of these products; however, thin films (150-300 A) of NiMoO4 on M0O3 (010) surfaces were highly active and selective. The sputtering technique has significant advantages for preparation and characterization of multicomponent catalysts compared to precipitation or impregnation routes.",

author = "Zou, {Joe Y.} and Schrader, {Glenn L.}",

note = "Funding Information: This work was performed with support from the Ames Laboratory which is operated for the U.S. Department of Energy by Iowa State University under Contract W-7405-ENG-82. Sputtered samples were prepared in the Center for Interfacial Materials and Crystallization. XPS data were obtained with the assistance of Dr. James Anderegg of the Ames Laboratory.",

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doi = "10.1016/S0167-2991(08)63394-7",

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T1 - Selective oxidation over structured multicomponent molybdate catalysts

AU - Zou, Joe Y.

AU - Schrader, Glenn L.

N1 - Funding Information: This work was performed with support from the Ames Laboratory which is operated for the U.S. Department of Energy by Iowa State University under Contract W-7405-ENG-82. Sputtered samples were prepared in the Center for Interfacial Materials and Crystallization. XPS data were obtained with the assistance of Dr. James Anderegg of the Ames Laboratory.

PY - 1994/1/1

Y1 - 1994/1/1

N2 - NiMoO4-MoO3 catalysts prepared by reactive sputtering were evaluated for the conversion of 1-butene to furan and maleic anhydride. As for precipitated catalysts, individual phases of NiMoO4 or MoO3 yielded very little of these products; however, thin films (150-300 A) of NiMoO4 on M0O3 (010) surfaces were highly active and selective. The sputtering technique has significant advantages for preparation and characterization of multicomponent catalysts compared to precipitation or impregnation routes.

AB - NiMoO4-MoO3 catalysts prepared by reactive sputtering were evaluated for the conversion of 1-butene to furan and maleic anhydride. As for precipitated catalysts, individual phases of NiMoO4 or MoO3 yielded very little of these products; however, thin films (150-300 A) of NiMoO4 on M0O3 (010) surfaces were highly active and selective. The sputtering technique has significant advantages for preparation and characterization of multicomponent catalysts compared to precipitation or impregnation routes.

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Selective oxidation over structured multicomponent molybdate catalysts

Abstract

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