Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

Pascal Jurt; Juan José Gamboa-Carballo; Clara Schweinzer; Daniel Himmelbauer; Debora Thöny; Thomas L. Gianetti; Monica Trincado; Hansjörg Grützmacher

doi:10.1039/d4dt01520g

Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

Pascal Jurt, Juan José Gamboa-Carballo, Clara Schweinzer, Daniel Himmelbauer, Debora Thöny, Thomas L. Gianetti, Monica Trincado, Hansjörg Grützmacher

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.

Original language	English (US)
Pages (from-to)	14212-14218
Number of pages	7
Journal	Dalton Transactions
Volume	53
Issue number	34
DOIs	https://doi.org/10.1039/d4dt01520g
State	Published - Aug 13 2024
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes",

abstract = "This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.",

author = "Pascal Jurt and Gamboa-Carballo, \{Juan Jos{\'e}\} and Clara Schweinzer and Daniel Himmelbauer and Debora Th{\"o}ny and Gianetti, \{Thomas L.\} and Monica Trincado and Hansj{\"o}rg Gr{\"u}tzmacher",

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doi = "10.1039/d4dt01520g",

language = "English (US)",

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T1 - Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

AU - Jurt, Pascal

AU - Gamboa-Carballo, Juan José

AU - Schweinzer, Clara

AU - Himmelbauer, Daniel

AU - Thöny, Debora

AU - Gianetti, Thomas L.

AU - Trincado, Monica

AU - Grützmacher, Hansjörg

PY - 2024/8/13

Y1 - 2024/8/13

N2 - This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.

AB - This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.

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U2 - 10.1039/d4dt01520g

DO - 10.1039/d4dt01520g

M3 - Article

C2 - 39140315

AN - SCOPUS:85201406037

SN - 1477-9226

VL - 53

SP - 14212

EP - 14218

JO - Dalton Transactions

JF - Dalton Transactions

IS - 34

ER -

Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

Abstract

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