Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

Pascal Jurt; Juan José Gamboa-Carballo; Clara Schweinzer; Daniel Himmelbauer; Debora Thöny; Thomas L. Gianetti; Monica Trincado; Hansjörg Grützmacher

doi:10.1039/d4dt01520g

Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

Pascal Jurt, Juan José Gamboa-Carballo, Clara Schweinzer, Daniel Himmelbauer, Debora Thöny, Thomas L. Gianetti, Monica Trincado, Hansjörg Grützmacher

Research output: Contribution to journal › Article › peer-review

Abstract

This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.

Original language	English (US)
Pages (from-to)	14212-14218
Number of pages	7
Journal	Dalton Transactions
Volume	53
Issue number	34
DOIs	https://doi.org/10.1039/d4dt01520g
State	Published - Aug 13 2024
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1039/d4dt01520g

Cite this

@article{709dc8c014db4a0ea802430be78d1a43,

title = "Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes",

abstract = "This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.",

author = "Pascal Jurt and Gamboa-Carballo, {Juan Jos{\'e}} and Clara Schweinzer and Daniel Himmelbauer and Debora Th{\"o}ny and Gianetti, {Thomas L.} and Monica Trincado and Hansj{\"o}rg Gr{\"u}tzmacher",

note = "Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry.",

year = "2024",

month = aug,

day = "13",

doi = "10.1039/d4dt01520g",

language = "English (US)",

volume = "53",

pages = "14212--14218",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "34",

}

TY - JOUR

T1 - Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

AU - Jurt, Pascal

AU - Gamboa-Carballo, Juan José

AU - Schweinzer, Clara

AU - Himmelbauer, Daniel

AU - Thöny, Debora

AU - Gianetti, Thomas L.

AU - Trincado, Monica

AU - Grützmacher, Hansjörg

PY - 2024/8/13

Y1 - 2024/8/13

N2 - This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.

AB - This report presents a selective synthetic approach towards borazine from ammonia borane using a dinuclear rhodium olefin homogeneous catalyst. The synthesis and spectroscopic characterization of a dirhodium ammonia borane complex as an intermediate provides insight into a possible mode of activation.

UR - http://www.scopus.com/inward/record.url?scp=85201406037&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85201406037&partnerID=8YFLogxK

U2 - 10.1039/d4dt01520g

DO - 10.1039/d4dt01520g

M3 - Article

C2 - 39140315

AN - SCOPUS:85201406037

SN - 1477-9226

VL - 53

SP - 14212

EP - 14218

JO - Dalton Transactions

JF - Dalton Transactions

IS - 34

ER -

Selective dehydrogenation of ammonia borane to borazine and derivatives by rhodium olefin complexes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this