Rotational transition and quadrupole coupling measurements on the NNO-HCN complex

D. J. Pauley; M. A. Roehrig; S. G. Kukolich

doi:10.1016/0009-2614(90)85070-S

Rotational transition and quadrupole coupling measurements on the NNO-HCN complex

D. J. Pauley, M. A. Roehrig, S. G. Kukolich

Chemistry and Biochemistry

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Abstract

Seven a-dipole and seven b-dipole transitions were measured for one isomer of the NNO-HCN complex using a pulsed-beam, Fourier transform microwave spectrometer. Rotational constants A+Δ_K=10326.3(4) MHz, B=2814.32(14) MHz and C=2201.00(12) MHz and distortion constants Δ_J=0.014(8) MHz and Δ_JK=0.14(6) MHz were obtained by fitting the observed transition frequencies. A quadrupole coupling strength due to the HCN nitrogen of eQq_aa=1.97±0.05 MHz was obtained by fitting low-J transitions. Approximate structural parameters are obtained using moments of inertia and quadrupole coupling data.

Original language	English (US)
Pages (from-to)	57-61
Number of pages	5
Journal	Chemical Physics Letters
Volume	167
Issue number	1-2
DOIs	https://doi.org/10.1016/0009-2614(90)85070-S
State	Published - Mar 16 1990

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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@article{80fe4355f63d44a2a95497b74ceb4d2c,

title = "Rotational transition and quadrupole coupling measurements on the NNO-HCN complex",

abstract = "Seven a-dipole and seven b-dipole transitions were measured for one isomer of the NNO-HCN complex using a pulsed-beam, Fourier transform microwave spectrometer. Rotational constants A+ΔK=10326.3(4) MHz, B=2814.32(14) MHz and C=2201.00(12) MHz and distortion constants ΔJ=0.014(8) MHz and ΔJK=0.14(6) MHz were obtained by fitting the observed transition frequencies. A quadrupole coupling strength due to the HCN nitrogen of eQqaa=1.97±0.05 MHz was obtained by fitting low-J transitions. Approximate structural parameters are obtained using moments of inertia and quadrupole coupling data.",

author = "Pauley, {D. J.} and Roehrig, {M. A.} and Kukolich, {S. G.}",

note = "Funding Information: Partial support for this research was provided by a Research Corporation, Research Opportunities Award to SGK. Acknowledgement is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this research. We thank Dave Dayton and Professor R.E. Miller for helpful discussions on this work.",

year = "1990",

month = mar,

day = "16",

doi = "10.1016/0009-2614(90)85070-S",

language = "English (US)",

volume = "167",

pages = "57--61",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "1-2",

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TY - JOUR

T1 - Rotational transition and quadrupole coupling measurements on the NNO-HCN complex

AU - Pauley, D. J.

AU - Roehrig, M. A.

AU - Kukolich, S. G.

N1 - Funding Information: Partial support for this research was provided by a Research Corporation, Research Opportunities Award to SGK. Acknowledgement is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this research. We thank Dave Dayton and Professor R.E. Miller for helpful discussions on this work.

PY - 1990/3/16

Y1 - 1990/3/16

N2 - Seven a-dipole and seven b-dipole transitions were measured for one isomer of the NNO-HCN complex using a pulsed-beam, Fourier transform microwave spectrometer. Rotational constants A+ΔK=10326.3(4) MHz, B=2814.32(14) MHz and C=2201.00(12) MHz and distortion constants ΔJ=0.014(8) MHz and ΔJK=0.14(6) MHz were obtained by fitting the observed transition frequencies. A quadrupole coupling strength due to the HCN nitrogen of eQqaa=1.97±0.05 MHz was obtained by fitting low-J transitions. Approximate structural parameters are obtained using moments of inertia and quadrupole coupling data.

AB - Seven a-dipole and seven b-dipole transitions were measured for one isomer of the NNO-HCN complex using a pulsed-beam, Fourier transform microwave spectrometer. Rotational constants A+ΔK=10326.3(4) MHz, B=2814.32(14) MHz and C=2201.00(12) MHz and distortion constants ΔJ=0.014(8) MHz and ΔJK=0.14(6) MHz were obtained by fitting the observed transition frequencies. A quadrupole coupling strength due to the HCN nitrogen of eQqaa=1.97±0.05 MHz was obtained by fitting low-J transitions. Approximate structural parameters are obtained using moments of inertia and quadrupole coupling data.

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U2 - 10.1016/0009-2614(90)85070-S

DO - 10.1016/0009-2614(90)85070-S

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SN - 0009-2614

VL - 167

SP - 57

EP - 61

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1-2

ER -

Rotational transition and quadrupole coupling measurements on the NNO-HCN complex

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