Rotational spectroscopy of 3 d transition-metal cyanides: Millimeter-wave studies of ZnCN (X2Σ+)

M. A. Brewster; L. M. Ziurys

doi:10.1063/1.1498466

Rotational spectroscopy of 3 d transition-metal cyanides: Millimeter-wave studies of ZnCN (X²Σ⁺)

M. A. Brewster, L. M. Ziurys

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Abstract

The rotational spectrum of the ZnCN radical in its ground electronic state was studied by using millimeter/sub-mm direct absorption techniques in the range of 339-543 GHz. The spectroscopic analysis were performed to determine the rotational, spin-rotation and l-type doubling parameters of the (000) and excited vibrational data of the given compounds. The results showed that the metal-carbon bond in ZnCN was weaker with respect to the bonds in CuCN and NiCN.

Original language	English (US)
Pages (from-to)	4853-4860
Number of pages	8
Journal	Journal of Chemical Physics
Volume	117
Issue number	10
DOIs	https://doi.org/10.1063/1.1498466
State	Published - Sep 8 2002

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "The rotational spectrum of the ZnCN radical in its ground electronic state was studied by using millimeter/sub-mm direct absorption techniques in the range of 339-543 GHz. The spectroscopic analysis were performed to determine the rotational, spin-rotation and l-type doubling parameters of the (000) and excited vibrational data of the given compounds. The results showed that the metal-carbon bond in ZnCN was weaker with respect to the bonds in CuCN and NiCN.",

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AU - Ziurys, L. M.

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Y1 - 2002/9/8

N2 - The rotational spectrum of the ZnCN radical in its ground electronic state was studied by using millimeter/sub-mm direct absorption techniques in the range of 339-543 GHz. The spectroscopic analysis were performed to determine the rotational, spin-rotation and l-type doubling parameters of the (000) and excited vibrational data of the given compounds. The results showed that the metal-carbon bond in ZnCN was weaker with respect to the bonds in CuCN and NiCN.

AB - The rotational spectrum of the ZnCN radical in its ground electronic state was studied by using millimeter/sub-mm direct absorption techniques in the range of 339-543 GHz. The spectroscopic analysis were performed to determine the rotational, spin-rotation and l-type doubling parameters of the (000) and excited vibrational data of the given compounds. The results showed that the metal-carbon bond in ZnCN was weaker with respect to the bonds in CuCN and NiCN.

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Rotational spectroscopy of 3 d transition-metal cyanides: Millimeter-wave studies of ZnCN (X²Σ⁺)

Abstract

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