Room-temperature hydrosilylation of the CF bond of vinyl fluoride catalyzed by osmium hydrides

Kenton B. Renkema; Ulrike Werner-Zwanziger; Mark D. Pagel; Kenneth G. Caulton

doi:10.1016/j.molcata.2004.07.028

Room-temperature hydrosilylation of the CF bond of vinyl fluoride catalyzed by osmium hydrides

Kenton B. Renkema, Ulrike Werner-Zwanziger, Mark D. Pagel, Kenneth G. Caulton

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The reactions of OsH(Ph)(CO)L ₂ (L = P ^tBu ₂Me) with HSiMe ₃, H ₂SiPh ₂ or H ₃SiPh produce benzene and OsH ₃(silyl)(CO)L ₂, which is characterized as a fac-H ₃OsP ₃ shape capped on the H ₃ face by the silyl group. For H ₂SiPh ₂ and H ₃SiPh, these reactions are shown proceed through an intermediate Os(H) ₂(silylene)(CO)L ₂ species. OsHF(CO)L ₂ reacts with these silanes to give the same OsH ₃ product (and silyl-F). These reactions can be combined to effect osmium catalysis of conversion of SiH + H ₂CCHF to fluorosilane and H ₂CCH ₂ from OsH ₃(SiMe ₃)(CO)L ₂, or from the catalyst precursor OsHF(CO)L ₂.

Original language	English (US)
Pages (from-to)	125-131
Number of pages	7
Journal	Journal of Molecular Catalysis A: Chemical
Volume	224
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2004.07.028
State	Published - Dec 15 2004
Externally published	Yes

Keywords

Fluorocarbon
Hydride
Osmium
Silanolysis

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

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10.1016/j.molcata.2004.07.028

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@article{0a164a528a0d4c83bd9cfd2563c1ee40,

title = "Room-temperature hydrosilylation of the CF bond of vinyl fluoride catalyzed by osmium hydrides",

abstract = "The reactions of OsH(Ph)(CO)L 2 (L = P tBu 2Me) with HSiMe 3, H 2SiPh 2 or H 3SiPh produce benzene and OsH 3(silyl)(CO)L 2, which is characterized as a fac-H 3OsP 3 shape capped on the H 3 face by the silyl group. For H 2SiPh 2 and H 3SiPh, these reactions are shown proceed through an intermediate Os(H) 2(silylene)(CO)L 2 species. OsHF(CO)L 2 reacts with these silanes to give the same OsH 3 product (and silyl-F). These reactions can be combined to effect osmium catalysis of conversion of SiH + H 2CCHF to fluorosilane and H 2CCH 2 from OsH 3(SiMe 3)(CO)L 2, or from the catalyst precursor OsHF(CO)L 2.",

keywords = "Fluorocarbon, Hydride, Osmium, Silanolysis",

author = "Renkema, \{Kenton B.\} and Ulrike Werner-Zwanziger and Pagel, \{Mark D.\} and Caulton, \{Kenneth G.\}",

note = "Funding Information: This work was supported by the National Science Foundation. ",

year = "2004",

month = dec,

day = "15",

doi = "10.1016/j.molcata.2004.07.028",

language = "English (US)",

volume = "224",

pages = "125--131",

journal = "Journal of Molecular Catalysis A: Chemical",

issn = "1381-1169",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Room-temperature hydrosilylation of the CF bond of vinyl fluoride catalyzed by osmium hydrides

AU - Renkema, Kenton B.

AU - Werner-Zwanziger, Ulrike

AU - Pagel, Mark D.

AU - Caulton, Kenneth G.

N1 - Funding Information: This work was supported by the National Science Foundation.

PY - 2004/12/15

Y1 - 2004/12/15

N2 - The reactions of OsH(Ph)(CO)L 2 (L = P tBu 2Me) with HSiMe 3, H 2SiPh 2 or H 3SiPh produce benzene and OsH 3(silyl)(CO)L 2, which is characterized as a fac-H 3OsP 3 shape capped on the H 3 face by the silyl group. For H 2SiPh 2 and H 3SiPh, these reactions are shown proceed through an intermediate Os(H) 2(silylene)(CO)L 2 species. OsHF(CO)L 2 reacts with these silanes to give the same OsH 3 product (and silyl-F). These reactions can be combined to effect osmium catalysis of conversion of SiH + H 2CCHF to fluorosilane and H 2CCH 2 from OsH 3(SiMe 3)(CO)L 2, or from the catalyst precursor OsHF(CO)L 2.

AB - The reactions of OsH(Ph)(CO)L 2 (L = P tBu 2Me) with HSiMe 3, H 2SiPh 2 or H 3SiPh produce benzene and OsH 3(silyl)(CO)L 2, which is characterized as a fac-H 3OsP 3 shape capped on the H 3 face by the silyl group. For H 2SiPh 2 and H 3SiPh, these reactions are shown proceed through an intermediate Os(H) 2(silylene)(CO)L 2 species. OsHF(CO)L 2 reacts with these silanes to give the same OsH 3 product (and silyl-F). These reactions can be combined to effect osmium catalysis of conversion of SiH + H 2CCHF to fluorosilane and H 2CCH 2 from OsH 3(SiMe 3)(CO)L 2, or from the catalyst precursor OsHF(CO)L 2.

KW - Fluorocarbon

KW - Hydride

KW - Osmium

KW - Silanolysis

UR - https://www.scopus.com/pages/publications/9144263910

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U2 - 10.1016/j.molcata.2004.07.028

DO - 10.1016/j.molcata.2004.07.028

M3 - Article

AN - SCOPUS:9144263910

SN - 1381-1169

VL - 224

SP - 125

EP - 131

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Room-temperature hydrosilylation of the CF bond of vinyl fluoride catalyzed by osmium hydrides

Abstract

Keywords

ASJC Scopus subject areas

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