Robust Molecular Dipole-Enabled Defect Passivation and Control of Energy-Level Alignment for High-Efficiency Perovskite Solar Cells

Bing Wang, Hong Li, Qingqing Dai, Meng Zhang, Zhigang Zou, Jean Luc Brédas, Zhiqun Lin

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

The ability to passivate defects and modulate the interface energy-level alignment (IEA) is key to boost the performance of perovskite solar cells (PSCs). Herein, we report a robust route that simultaneously allows defect passivation and reduced energy difference between perovskite and hole transport layer (HTL) via the judicious placement of polar chlorine-terminated silane molecules at the interface. Density functional theory (DFT) points to effective passivation of the halide vacancies on perovskite surface by the silane chlorine atoms. An integrated experimental and DFT study demonstrates that the dipole layer formed by the silane molecules decreases the perovskite work function, imparting an Ohmic character to the perovskite/HTL contact. The corresponding PSCs manifest a nearly 20 % increase in power conversion efficiency over pristine devices and a markedly enhanced device stability. As such, the use of polar molecules to passivate defects and tailor the IEA in PSCs presents a promising platform to advance the performance of PSCs.

Original languageEnglish (US)
Pages (from-to)17664-17670
Number of pages7
JournalAngewandte Chemie - International Edition
Volume60
Issue number32
DOIs
StatePublished - Aug 2 2021
Externally publishedYes

Keywords

  • chlorosilane molecules
  • defect passivation
  • dipole moment
  • interface energy level alignment
  • perovskite solar cells

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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