RHEED and optical characterization of ordered multilayers of phthalocyanine{plus 45 degree rule}C60 and phthalocyanine/perylene-tetracarboxylicdianhydride (PTCDA)

M. L. Anderson; V. S. Williams; T. J. Schuerlein; G. E. Collins; C. D. England; L. K. Chau; P. A. Lee; K. W. Nebesny; N. R. Armstrong

doi:10.1016/0039-6028(94)90452-9

RHEED and optical characterization of ordered multilayers of phthalocyanine{plus 45 degree rule}C₆₀ and phthalocyanine/perylene-tetracarboxylicdianhydride (PTCDA)

M. L. Anderson, V. S. Williams, T. J. Schuerlein, G. E. Collins, C. D. England, L. K. Chau, P. A. Lee, K. W. Nebesny, N. R. Armstrong

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Ordered monolayers → multilayers of trivalent metal phthalocyanines, C₆₀, and the perylenetetracarboxylic dianhydride (PTCDA) have been formed by molecular beam epitaxy processes on both single crystal MoS₂ and SnS₂, and on MBE-deposited SnS₂ thin films. The bulk packing structures for the trivalent metal chloride phthalocyanines lend themselves to layered growth during deposition, as do the structures for C₆₀ and PTCDA. RHEED data collected during the formation of [(InPc-Cl)_{1-4 ML}/(C₆₀)_{1-4 ML}]_1-20/SnS₂/mica multilayers suggests that the structures observed during the formation of single component thin films can be sustained during multilayer formation, up to several lattice periods. Absorbance spectra of Pc/C₆₀ and Pc/PTCDA multilayers show Pc Q-bands with maxima and full widths consistent with the formation of ordered Pc layers, provided that the Pc layer thickness is kept at 1-2 monolayers throughout the formation of the multilayer assembly.

Original language	English (US)
Pages (from-to)	551-558
Number of pages	8
Journal	Surface Science
Volume	307-309
Issue number	PART A
DOIs	https://doi.org/10.1016/0039-6028(94)90452-9
State	Published - Apr 20 1994
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films
Materials Chemistry

Access to Document

10.1016/0039-6028(94)90452-9

Cite this

Anderson, M. L., Williams, V. S., Schuerlein, T. J., Collins, G. E., England, C. D., Chau, L. K., Lee, P. A., Nebesny, K. W., & Armstrong, N. R. (1994). RHEED and optical characterization of ordered multilayers of phthalocyanine{plus 45 degree rule}C₆₀ and phthalocyanine/perylene-tetracarboxylicdianhydride (PTCDA). Surface Science, 307-309(PART A), 551-558. https://doi.org/10.1016/0039-6028(94)90452-9

Anderson, ML, Williams, VS, Schuerlein, TJ, Collins, GE, England, CD, Chau, LK, Lee, PA, Nebesny, KW & Armstrong, NR 1994, 'RHEED and optical characterization of ordered multilayers of phthalocyanine{plus 45 degree rule}C₆₀ and phthalocyanine/perylene-tetracarboxylicdianhydride (PTCDA)', Surface Science, vol. 307-309, no. PART A, pp. 551-558. https://doi.org/10.1016/0039-6028(94)90452-9

@article{f897d0489e2046fd847ad2c3d0927e65,

title = "RHEED and optical characterization of ordered multilayers of phthalocyanine{plus 45 degree rule}C60 and phthalocyanine/perylene-tetracarboxylicdianhydride (PTCDA)",

abstract = "Ordered monolayers → multilayers of trivalent metal phthalocyanines, C60, and the perylenetetracarboxylic dianhydride (PTCDA) have been formed by molecular beam epitaxy processes on both single crystal MoS2 and SnS2, and on MBE-deposited SnS2 thin films. The bulk packing structures for the trivalent metal chloride phthalocyanines lend themselves to layered growth during deposition, as do the structures for C60 and PTCDA. RHEED data collected during the formation of [(InPc-Cl)1-4 ML/(C60)1-4 ML]1-20/SnS2/mica multilayers suggests that the structures observed during the formation of single component thin films can be sustained during multilayer formation, up to several lattice periods. Absorbance spectra of Pc/C60 and Pc/PTCDA multilayers show Pc Q-bands with maxima and full widths consistent with the formation of ordered Pc layers, provided that the Pc layer thickness is kept at 1-2 monolayers throughout the formation of the multilayer assembly.",

author = "Anderson, {M. L.} and Williams, {V. S.} and Schuerlein, {T. J.} and Collins, {G. E.} and England, {C. D.} and Chau, {L. K.} and Lee, {P. A.} and Nebesny, {K. W.} and Armstrong, {N. R.}",

note = "Funding Information: This researchw as supportedi n part by grants from the National Science Foundation (Chemistry and Small Grants for ExploratoryR esearch), the Air Force Office of Scientific Research,a nd by the Materials CharacterizationP rogram,S tate of Arizona.",

year = "1994",

month = apr,

day = "20",

doi = "10.1016/0039-6028(94)90452-9",

language = "English (US)",

volume = "307-309",

pages = "551--558",

journal = "Surface Science",

issn = "0039-6028",

publisher = "Elsevier B.V.",

number = "PART A",

}

TY - JOUR

T1 - RHEED and optical characterization of ordered multilayers of phthalocyanine{plus 45 degree rule}C60 and phthalocyanine/perylene-tetracarboxylicdianhydride (PTCDA)

AU - Anderson, M. L.

AU - Williams, V. S.

AU - Schuerlein, T. J.

AU - Collins, G. E.

AU - England, C. D.

AU - Chau, L. K.

AU - Lee, P. A.

AU - Nebesny, K. W.

AU - Armstrong, N. R.

N1 - Funding Information: This researchw as supportedi n part by grants from the National Science Foundation (Chemistry and Small Grants for ExploratoryR esearch), the Air Force Office of Scientific Research,a nd by the Materials CharacterizationP rogram,S tate of Arizona.

PY - 1994/4/20

Y1 - 1994/4/20

N2 - Ordered monolayers → multilayers of trivalent metal phthalocyanines, C60, and the perylenetetracarboxylic dianhydride (PTCDA) have been formed by molecular beam epitaxy processes on both single crystal MoS2 and SnS2, and on MBE-deposited SnS2 thin films. The bulk packing structures for the trivalent metal chloride phthalocyanines lend themselves to layered growth during deposition, as do the structures for C60 and PTCDA. RHEED data collected during the formation of [(InPc-Cl)1-4 ML/(C60)1-4 ML]1-20/SnS2/mica multilayers suggests that the structures observed during the formation of single component thin films can be sustained during multilayer formation, up to several lattice periods. Absorbance spectra of Pc/C60 and Pc/PTCDA multilayers show Pc Q-bands with maxima and full widths consistent with the formation of ordered Pc layers, provided that the Pc layer thickness is kept at 1-2 monolayers throughout the formation of the multilayer assembly.

AB - Ordered monolayers → multilayers of trivalent metal phthalocyanines, C60, and the perylenetetracarboxylic dianhydride (PTCDA) have been formed by molecular beam epitaxy processes on both single crystal MoS2 and SnS2, and on MBE-deposited SnS2 thin films. The bulk packing structures for the trivalent metal chloride phthalocyanines lend themselves to layered growth during deposition, as do the structures for C60 and PTCDA. RHEED data collected during the formation of [(InPc-Cl)1-4 ML/(C60)1-4 ML]1-20/SnS2/mica multilayers suggests that the structures observed during the formation of single component thin films can be sustained during multilayer formation, up to several lattice periods. Absorbance spectra of Pc/C60 and Pc/PTCDA multilayers show Pc Q-bands with maxima and full widths consistent with the formation of ordered Pc layers, provided that the Pc layer thickness is kept at 1-2 monolayers throughout the formation of the multilayer assembly.

UR - http://www.scopus.com/inward/record.url?scp=19244377989&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=19244377989&partnerID=8YFLogxK

U2 - 10.1016/0039-6028(94)90452-9

DO - 10.1016/0039-6028(94)90452-9

M3 - Article

AN - SCOPUS:19244377989

SN - 0039-6028

VL - 307-309

SP - 551

EP - 558

JO - Surface Science

JF - Surface Science

IS - PART A

ER -

RHEED and optical characterization of ordered multilayers of phthalocyanine{plus 45 degree rule}C₆₀ and phthalocyanine/perylene-tetracarboxylicdianhydride (PTCDA)

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this