Regioselective N/C-heterocyclization of allenylindium bromide across aryl azides: One-pot synthesis of 5-methyl-1,2,3-triazoles

Abid H. Banday; Victor J. Hruby

doi:10.1055/s-0034-1378327

Regioselective N/C-heterocyclization of allenylindium bromide across aryl azides: One-pot synthesis of 5-methyl-1,2,3-triazoles

Abid H. Banday, Victor J. Hruby

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

An unprecedented, one-pot regioselective synthesis of 1,5-disubstituted 1,2,3-triazoles through N/C-heterocyclization of allenylindium bromide across aryl azides is described. The synthesis is carried out under mild conditions in aqueous medium and proceeds regioselectively in moderate to good yields.

Original language	English (US)
Article number	st-2014-r0218-l
Pages (from-to)	1859-1862
Number of pages	4
Journal	Synlett
Volume	25
Issue number	13
DOIs	https://doi.org/10.1055/s-0034-1378327
State	Published - Aug 2014
Externally published	Yes

Keywords

1,2,3-triazoles
allenylindium bromide
aryl azides
heterocyclization
regioselective reactions

ASJC Scopus subject areas

Organic Chemistry

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10.1055/s-0034-1378327

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title = "Regioselective N/C-heterocyclization of allenylindium bromide across aryl azides: One-pot synthesis of 5-methyl-1,2,3-triazoles",

abstract = "An unprecedented, one-pot regioselective synthesis of 1,5-disubstituted 1,2,3-triazoles through N/C-heterocyclization of allenylindium bromide across aryl azides is described. The synthesis is carried out under mild conditions in aqueous medium and proceeds regioselectively in moderate to good yields.",

keywords = "1,2,3-triazoles, allenylindium bromide, aryl azides, heterocyclization, regioselective reactions",

author = "Banday, {Abid H.} and Hruby, {Victor J.}",

year = "2014",

month = aug,

doi = "10.1055/s-0034-1378327",

language = "English (US)",

volume = "25",

pages = "1859--1862",

journal = "Synlett",

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T2 - One-pot synthesis of 5-methyl-1,2,3-triazoles

AU - Banday, Abid H.

AU - Hruby, Victor J.

PY - 2014/8

Y1 - 2014/8

N2 - An unprecedented, one-pot regioselective synthesis of 1,5-disubstituted 1,2,3-triazoles through N/C-heterocyclization of allenylindium bromide across aryl azides is described. The synthesis is carried out under mild conditions in aqueous medium and proceeds regioselectively in moderate to good yields.

AB - An unprecedented, one-pot regioselective synthesis of 1,5-disubstituted 1,2,3-triazoles through N/C-heterocyclization of allenylindium bromide across aryl azides is described. The synthesis is carried out under mild conditions in aqueous medium and proceeds regioselectively in moderate to good yields.

KW - 1,2,3-triazoles

KW - allenylindium bromide

KW - aryl azides

KW - heterocyclization

KW - regioselective reactions

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ER -

Regioselective N/C-heterocyclization of allenylindium bromide across aryl azides: One-pot synthesis of 5-methyl-1,2,3-triazoles

Abstract

Keywords

ASJC Scopus subject areas

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