Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Aiswarya Abhisek Mohapatra; Waleed Kuar Yual; Yadong Zhang; Anton Aleksandrovich Samoylov; Jonathan Thurston; Casey M. Davis; Declan P. McCarthy; Adam D. Printz; Michael F. Toney; Erin L. Ratcliff; Neal R. Armstrong; Ann L. Greenaway; Stephen Barlow; Seth R. Marder

doi:10.1039/d3cc05391a

Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Aiswarya Abhisek Mohapatra
, Waleed Kuar Yual
, Yadong Zhang
, Anton Aleksandrovich Samoylov
, Jonathan Thurston
, Casey M. Davis
, Declan P. McCarthy
, Adam D. Printz
, Michael F. Toney
, Erin L. Ratcliff
, Neal R. Armstrong
, Ann L. Greenaway
, Stephen Barlow
, Seth R. Marder

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

Original language	English (US)
Pages (from-to)	988-991
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	8
DOIs	https://doi.org/10.1039/d3cc05391a
State	Published - Dec 20 2023

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d3cc05391a

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Mohapatra, A. A., Yual, W. K., Zhang, Y., Samoylov, A. A., Thurston, J., Davis, C. M., McCarthy, D. P., Printz, A. D., Toney, M. F., Ratcliff, E. L., Armstrong, N. R., Greenaway, A. L., Barlow, S., & Marder, S. R. (2023). Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications. Chemical Communications, 60(8), 988-991. https://doi.org/10.1039/d3cc05391a

Mohapatra, AA, Yual, WK, Zhang, Y, Samoylov, AA, Thurston, J, Davis, CM, McCarthy, DP, Printz, AD, Toney, MF, Ratcliff, EL, Armstrong, NR, Greenaway, AL, Barlow, S & Marder, SR 2023, 'Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications', Chemical Communications, vol. 60, no. 8, pp. 988-991. https://doi.org/10.1039/d3cc05391a

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abstract = "Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.",

author = "Mohapatra, \{Aiswarya Abhisek\} and Yual, \{Waleed Kuar\} and Yadong Zhang and Samoylov, \{Anton Aleksandrovich\} and Jonathan Thurston and Davis, \{Casey M.\} and McCarthy, \{Declan P.\} and Printz, \{Adam D.\} and Toney, \{Michael F.\} and Ratcliff, \{Erin L.\} and Armstrong, \{Neal R.\} and Greenaway, \{Ann L.\} and Stephen Barlow and Marder, \{Seth R.\}",

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AU - Mohapatra, Aiswarya Abhisek

AU - Yual, Waleed Kuar

AU - Zhang, Yadong

AU - Samoylov, Anton Aleksandrovich

AU - Thurston, Jonathan

AU - Davis, Casey M.

AU - McCarthy, Declan P.

AU - Printz, Adam D.

AU - Toney, Michael F.

AU - Ratcliff, Erin L.

AU - Armstrong, Neal R.

AU - Greenaway, Ann L.

AU - Barlow, Stephen

AU - Marder, Seth R.

PY - 2023/12/20

Y1 - 2023/12/20

N2 - Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

AB - Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

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EP - 991

JO - Chemical Communications

JF - Chemical Communications

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ER -

Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Abstract

ASJC Scopus subject areas

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