Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Aiswarya Abhisek Mohapatra; Waleed Kuar Yual; Yadong Zhang; Anton Aleksandrovich Samoylov; Jonathan Thurston; Casey M. Davis; Declan P. McCarthy; Adam D. Printz; Michael F. Toney; Erin L. Ratcliff; Neal R Armstrong; Ann L. Greenaway; Stephen Barlow; Seth R. Marder

doi:10.1039/d3cc05391a

Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Aiswarya Abhisek Mohapatra, Waleed Kuar Yual, Yadong Zhang, Anton Aleksandrovich Samoylov, Jonathan Thurston, Casey M. Davis, Declan P. McCarthy, Adam D. Printz, Michael F. Toney, Erin L. Ratcliff, Neal R Armstrong, Ann L. Greenaway, Stephen Barlow, Seth R. Marder

Research output: Contribution to journal › Article › peer-review

Abstract

Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

Original language	English (US)
Pages (from-to)	988-991
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	8
DOIs	https://doi.org/10.1039/d3cc05391a
State	Published - Dec 20 2023

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d3cc05391a

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Mohapatra, A. A., Yual, W. K., Zhang, Y., Samoylov, A. A., Thurston, J., Davis, C. M., McCarthy, D. P., Printz, A. D., Toney, M. F., Ratcliff, E. L., Armstrong, N. R., Greenaway, A. L., Barlow, S., & Marder, S. R. (2023). Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications. Chemical Communications, 60(8), 988-991. https://doi.org/10.1039/d3cc05391a

Mohapatra, AA, Yual, WK, Zhang, Y, Samoylov, AA, Thurston, J, Davis, CM, McCarthy, DP, Printz, AD, Toney, MF, Ratcliff, EL, Armstrong, NR, Greenaway, AL, Barlow, S & Marder, SR 2023, 'Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications', Chemical Communications, vol. 60, no. 8, pp. 988-991. https://doi.org/10.1039/d3cc05391a

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abstract = "Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.",

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doi = "10.1039/d3cc05391a",

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AU - Mohapatra, Aiswarya Abhisek

AU - Yual, Waleed Kuar

AU - Zhang, Yadong

AU - Samoylov, Anton Aleksandrovich

AU - Thurston, Jonathan

AU - Davis, Casey M.

AU - McCarthy, Declan P.

AU - Printz, Adam D.

AU - Toney, Michael F.

AU - Ratcliff, Erin L.

AU - Armstrong, Neal R

AU - Greenaway, Ann L.

AU - Barlow, Stephen

AU - Marder, Seth R.

PY - 2023/12/20

Y1 - 2023/12/20

N2 - Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

AB - Delamination of the electron-transporting polymer N2200 from indium tin oxide (ITO) in aqueous electrolytes is mitigated by modifying ITO with an azide-functionalized phosphonic acid (PA) which, upon UV irradiation, reacts with the polymer. The optical, electrochemical, and spectroelectrochemical properties of N2200 thin films are retained in aqueous and non-aqueous media.

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Reducing delamination of an electron-transporting polymer from a metal oxide for electrochemical applications

Abstract

ASJC Scopus subject areas

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