Red-Light-Induced N, N'-Dipropyl-1,13-dimethoxyquinacridinium-Catalyzed [3+2] Cycloaddition of Cyclopropylamines with Alkenes or Alkynes

Savannah M. Stull; Liangyong Mei; Thomas L. Gianetti

doi:10.1055/a-1665-9220

Red-Light-Induced N, N'-Dipropyl-1,13-dimethoxyquinacridinium-Catalyzed [3+2] Cycloaddition of Cyclopropylamines with Alkenes or Alkynes

Savannah M. Stull, Liangyong Mei, Thomas L. Gianetti

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A red-light-mediated [3+2] annulation of cyclopropylamines with akenes or alkynes in the presence of N,N'-dipropyl-1,13-dimethoxyquinacridinium is reported. An array of cyclopentane or cyclopentene derivatives with diverse functional groups have been obtained in moderate to excellent yields under mild conditions.

Original language	English (US)
Journal	Synlett
DOIs	https://doi.org/10.1055/a-1665-9220
State	Accepted/In press - 2021

Keywords

[3+2] cycloaddition
alkenes
alkynes
cyclopropylamines
dipropyldimethoxyquinacridinium
photoredox catalysis

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1055/a-1665-9220

Cite this

@article{5df7be5b00be421aadc5f8c11e95b802,

title = "Red-Light-Induced N, N'-Dipropyl-1,13-dimethoxyquinacridinium-Catalyzed [3+2] Cycloaddition of Cyclopropylamines with Alkenes or Alkynes",

abstract = "A red-light-mediated [3+2] annulation of cyclopropylamines with akenes or alkynes in the presence of N,N'-dipropyl-1,13-dimethoxyquinacridinium is reported. An array of cyclopentane or cyclopentene derivatives with diverse functional groups have been obtained in moderate to excellent yields under mild conditions. ",

keywords = "[3+2] cycloaddition, alkenes, alkynes, cyclopropylamines, dipropyldimethoxyquinacridinium, photoredox catalysis",

author = "Stull, {Savannah M.} and Liangyong Mei and Gianetti, {Thomas L.}",

year = "2021",

doi = "10.1055/a-1665-9220",

language = "English (US)",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

}

TY - JOUR

T1 - Red-Light-Induced N, N'-Dipropyl-1,13-dimethoxyquinacridinium-Catalyzed [3+2] Cycloaddition of Cyclopropylamines with Alkenes or Alkynes

AU - Stull, Savannah M.

AU - Mei, Liangyong

AU - Gianetti, Thomas L.

PY - 2021

Y1 - 2021

N2 - A red-light-mediated [3+2] annulation of cyclopropylamines with akenes or alkynes in the presence of N,N'-dipropyl-1,13-dimethoxyquinacridinium is reported. An array of cyclopentane or cyclopentene derivatives with diverse functional groups have been obtained in moderate to excellent yields under mild conditions.

AB - A red-light-mediated [3+2] annulation of cyclopropylamines with akenes or alkynes in the presence of N,N'-dipropyl-1,13-dimethoxyquinacridinium is reported. An array of cyclopentane or cyclopentene derivatives with diverse functional groups have been obtained in moderate to excellent yields under mild conditions.

KW - [3+2] cycloaddition

KW - alkenes

KW - alkynes

KW - cyclopropylamines

KW - dipropyldimethoxyquinacridinium

KW - photoredox catalysis

UR - http://www.scopus.com/inward/record.url?scp=85119845192&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85119845192&partnerID=8YFLogxK

U2 - 10.1055/a-1665-9220

DO - 10.1055/a-1665-9220

M3 - Article

AN - SCOPUS:85119845192

JO - Synlett

JF - Synlett

SN - 0936-5214

ER -

Red-Light-Induced N, N'-Dipropyl-1,13-dimethoxyquinacridinium-Catalyzed [3+2] Cycloaddition of Cyclopropylamines with Alkenes or Alkynes

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this