Red-Light-Induced N, N'-Dipropyl-1,13-dimethoxyquinacridinium-Catalyzed [3+2] Cycloaddition of Cyclopropylamines with Alkenes or Alkynes

Savannah M. Stull, Liangyong Mei, Thomas L. Gianetti

Research output: Contribution to journalArticlepeer-review

Abstract

A red-light-mediated [3+2] annulation of cyclopropylamines with akenes or alkynes in the presence of N,N'-dipropyl-1,13-dimethoxyquinacridinium is reported. An array of cyclopentane or cyclopentene derivatives with diverse functional groups have been obtained in moderate to excellent yields under mild conditions.

Original languageEnglish (US)
JournalSynlett
DOIs
StateAccepted/In press - 2021

Keywords

  • [3+2] cycloaddition
  • alkenes
  • alkynes
  • cyclopropylamines
  • dipropyldimethoxyquinacridinium
  • photoredox catalysis

ASJC Scopus subject areas

  • Organic Chemistry

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