Raman spectroscopic investigations of the acid‐base forms of dithizone

Jeanne E. Pemberton; Richard P. Buck

doi:10.1002/jrs.1250120112

Raman spectroscopic investigations of the acid‐base forms of dithizone

Jeanne E. Pemberton, Richard P. Buck

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Raman spectra of three forms of dithizone are presented. Significant structural changes are indicated in the Raman spectra when a proton is added or lost from neutral dithizone (H₂Dz) to form the corresponding conjugate acid of dithizone (H₃Dz⁺) and the dithizone anion (HDz⁻), respectively. These spectral changes are correlated with the structures previously proposed for these species.

Original language	English (US)
Pages (from-to)	76-81
Number of pages	6
Journal	Journal of Raman Spectroscopy
Volume	12
Issue number	1
DOIs	https://doi.org/10.1002/jrs.1250120112
State	Published - Feb 1982
Externally published	Yes

ASJC Scopus subject areas

General Materials Science
Spectroscopy

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title = "Raman spectroscopic investigations of the acid‐base forms of dithizone",

abstract = "Raman spectra of three forms of dithizone are presented. Significant structural changes are indicated in the Raman spectra when a proton is added or lost from neutral dithizone (H2Dz) to form the corresponding conjugate acid of dithizone (H3Dz+) and the dithizone anion (HDz−), respectively. These spectral changes are correlated with the structures previously proposed for these species.",

author = "Pemberton, {Jeanne E.} and Buck, {Richard P.}",

year = "1982",

month = feb,

doi = "10.1002/jrs.1250120112",

language = "English (US)",

volume = "12",

pages = "76--81",

journal = "Journal of Raman Spectroscopy",

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T1 - Raman spectroscopic investigations of the acid‐base forms of dithizone

AU - Pemberton, Jeanne E.

AU - Buck, Richard P.

PY - 1982/2

Y1 - 1982/2

N2 - Raman spectra of three forms of dithizone are presented. Significant structural changes are indicated in the Raman spectra when a proton is added or lost from neutral dithizone (H2Dz) to form the corresponding conjugate acid of dithizone (H3Dz+) and the dithizone anion (HDz−), respectively. These spectral changes are correlated with the structures previously proposed for these species.

AB - Raman spectra of three forms of dithizone are presented. Significant structural changes are indicated in the Raman spectra when a proton is added or lost from neutral dithizone (H2Dz) to form the corresponding conjugate acid of dithizone (H3Dz+) and the dithizone anion (HDz−), respectively. These spectral changes are correlated with the structures previously proposed for these species.

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DO - 10.1002/jrs.1250120112

M3 - Article

AN - SCOPUS:84986760558

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JO - Journal of Raman Spectroscopy

JF - Journal of Raman Spectroscopy

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ER -

Raman spectroscopic investigations of the acid‐base forms of dithizone

Abstract

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