Raman scattering study of the Ba1-xRxF2+x superionic conductors

M. Kolesik; B. P. Sobolev

doi:10.1016/0167-2738(91)90255-A

Raman scattering study of the Ba_1-xR_xF_2+x superionic conductors

M. Kolesik, B. P. Sobolev

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The nonstoichiometric solid solutions Ba_1-xR_xF_2+x (where R = Ce, Pr, Gd, Tb; and 0.10≤x≤0.30) are studied by Raman spectroscopy. Besides the main Raman peak, two additional bands are observed on its high-frequency side. A new interpretation for the extra-peaks, based on the cluster structure, is proposed. The observed vibrations seem to be connected with 8:12: (0, 1, 2) clusters.

Original language	English (US)
Pages (from-to)	325-329
Number of pages	5
Journal	Solid State Ionics
Volume	47
Issue number	3-4
DOIs	https://doi.org/10.1016/0167-2738(91)90255-A
State	Published - Sep 1991
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Raman scattering study of the Ba1-xRxF2+x superionic conductors",

abstract = "The nonstoichiometric solid solutions Ba1-xRxF2+x (where R = Ce, Pr, Gd, Tb; and 0.10≤x≤0.30) are studied by Raman spectroscopy. Besides the main Raman peak, two additional bands are observed on its high-frequency side. A new interpretation for the extra-peaks, based on the cluster structure, is proposed. The observed vibrations seem to be connected with 8:12: (0, 1, 2) clusters.",

author = "M. Kolesik and Sobolev, {B. P.}",

year = "1991",

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AU - Kolesik, M.

AU - Sobolev, B. P.

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N2 - The nonstoichiometric solid solutions Ba1-xRxF2+x (where R = Ce, Pr, Gd, Tb; and 0.10≤x≤0.30) are studied by Raman spectroscopy. Besides the main Raman peak, two additional bands are observed on its high-frequency side. A new interpretation for the extra-peaks, based on the cluster structure, is proposed. The observed vibrations seem to be connected with 8:12: (0, 1, 2) clusters.

AB - The nonstoichiometric solid solutions Ba1-xRxF2+x (where R = Ce, Pr, Gd, Tb; and 0.10≤x≤0.30) are studied by Raman spectroscopy. Besides the main Raman peak, two additional bands are observed on its high-frequency side. A new interpretation for the extra-peaks, based on the cluster structure, is proposed. The observed vibrations seem to be connected with 8:12: (0, 1, 2) clusters.

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JO - Solid State Ionics

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IS - 3-4

ER -

Raman scattering study of the Ba_1-xR_xF_2+x superionic conductors

Abstract

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