Quantitative surface electron spectroscopies: Application to the study of corrosion of metals and glasses

B. L. Maschhoff; K. R. Zavadil; K. W. Nebesny; N. R. Armstrong

doi:10.1116/1.575028

Quantitative surface electron spectroscopies: Application to the study of corrosion of metals and glasses

B. L. Maschhoff, K. R. Zavadil, K. W. Nebesny, N. R. Armstrong

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The surface chemical reactions of extremely reactive metals such as lithium have been explored using x-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES), Corrosion processes which occur at the lithium surface, or corrosion reactions occurring at lithium/glass interfaces, are difficult to characterize by normal ex situ analyses which may damage the interface of interest. Starting with atomically clean surfaces, XPS and AES can be used to help construct a surface with controlled composition passive layers which can then be immersed into electrochemical environments and systematicaly studied. Careful analysis of the XPS or AES data is needed to provide reliable molecular information and quantitation of the actual metal surface regions.

Original language	English (US)
Pages (from-to)	907-913
Number of pages	7
Journal	Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films
Volume	6
Issue number	3
DOIs	https://doi.org/10.1116/1.575028
State	Published - May 1988
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics
Surfaces and Interfaces
Surfaces, Coatings and Films

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abstract = "The surface chemical reactions of extremely reactive metals such as lithium have been explored using x-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES), Corrosion processes which occur at the lithium surface, or corrosion reactions occurring at lithium/glass interfaces, are difficult to characterize by normal ex situ analyses which may damage the interface of interest. Starting with atomically clean surfaces, XPS and AES can be used to help construct a surface with controlled composition passive layers which can then be immersed into electrochemical environments and systematicaly studied. Careful analysis of the XPS or AES data is needed to provide reliable molecular information and quantitation of the actual metal surface regions.",

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AU - Nebesny, K. W.

AU - Armstrong, N. R.

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AB - The surface chemical reactions of extremely reactive metals such as lithium have been explored using x-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES), Corrosion processes which occur at the lithium surface, or corrosion reactions occurring at lithium/glass interfaces, are difficult to characterize by normal ex situ analyses which may damage the interface of interest. Starting with atomically clean surfaces, XPS and AES can be used to help construct a surface with controlled composition passive layers which can then be immersed into electrochemical environments and systematicaly studied. Careful analysis of the XPS or AES data is needed to provide reliable molecular information and quantitation of the actual metal surface regions.

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Quantitative surface electron spectroscopies: Application to the study of corrosion of metals and glasses

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