Quadrupole coupling measurements on35CINO

M. A. Roehrig; S. G. Kukolich

doi:10.1080/00268979200101271

Quadrupole coupling measurements on³⁵CINO

M. A. Roehrig, S. G. Kukolich

Chemistry and Biochemistry

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Abstract

Hyperfine structure for J = 0 → 1 and J = 1 → 2 transitions of³⁵CINO was measured using a pulsed-beam, Fourier transform spectrometer and beam- maser spectrometer. The high resolution microwave spectra were analysed to obtain eQq_bb(Cl) = -49·05(4), eQq_bb(Cl) = 30·0(4·0), eQq_aa(N) = 0·98(6) and eQq_bb(N) = -4·78(22) MHz. The quadrupole coupling values are discussed in relation to results in other small molecules and nitrosyl complexes. Rotational constants obtained from the measurements were B = 5737·70(6) and C = 5376·32(6) MHz.

Original language	English (US)
Pages (from-to)	221-227
Number of pages	7
Journal	Molecular Physics
Volume	76
Issue number	1
DOIs	https://doi.org/10.1080/00268979200101271
State	Published - May 1992

ASJC Scopus subject areas

Biophysics
Molecular Biology
Condensed Matter Physics
Physical and Theoretical Chemistry

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10.1080/00268979200101271

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@article{efb0730fa6df4a10a90a9d51a4bd1eac,

title = "Quadrupole coupling measurements on35CINO",

abstract = "Hyperfine structure for J = 0 → 1 and J = 1 → 2 transitions of35CINO was measured using a pulsed-beam, Fourier transform spectrometer and beam- maser spectrometer. The high resolution microwave spectra were analysed to obtain eQqbb(Cl) = -49·05(4), eQqbb(Cl) = 30·0(4·0), eQqaa(N) = 0·98(6) and eQqbb(N) = -4·78(22) MHz. The quadrupole coupling values are discussed in relation to results in other small molecules and nitrosyl complexes. Rotational constants obtained from the measurements were B = 5737·70(6) and C = 5376·32(6) MHz.",

author = "Roehrig, {M. A.} and Kukolich, {S. G.}",

note = "Funding Information: Partial support for this research was provided by a Research Corporation, Flinn Foundation Award to S. G. Kukolich. Acknowledgement is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this research. John Rund provided helpful advice on CINO preparation.",

year = "1992",

month = may,

doi = "10.1080/00268979200101271",

language = "English (US)",

volume = "76",

pages = "221--227",

journal = "Molecular Physics",

issn = "0026-8976",

publisher = "Taylor and Francis Ltd.",

number = "1",

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TY - JOUR

T1 - Quadrupole coupling measurements on35CINO

AU - Roehrig, M. A.

AU - Kukolich, S. G.

N1 - Funding Information: Partial support for this research was provided by a Research Corporation, Flinn Foundation Award to S. G. Kukolich. Acknowledgement is made to the donors of the Petroleum Research Fund, administered by the American Chemical Society, for partial support of this research. John Rund provided helpful advice on CINO preparation.

PY - 1992/5

Y1 - 1992/5

N2 - Hyperfine structure for J = 0 → 1 and J = 1 → 2 transitions of35CINO was measured using a pulsed-beam, Fourier transform spectrometer and beam- maser spectrometer. The high resolution microwave spectra were analysed to obtain eQqbb(Cl) = -49·05(4), eQqbb(Cl) = 30·0(4·0), eQqaa(N) = 0·98(6) and eQqbb(N) = -4·78(22) MHz. The quadrupole coupling values are discussed in relation to results in other small molecules and nitrosyl complexes. Rotational constants obtained from the measurements were B = 5737·70(6) and C = 5376·32(6) MHz.

AB - Hyperfine structure for J = 0 → 1 and J = 1 → 2 transitions of35CINO was measured using a pulsed-beam, Fourier transform spectrometer and beam- maser spectrometer. The high resolution microwave spectra were analysed to obtain eQqbb(Cl) = -49·05(4), eQqbb(Cl) = 30·0(4·0), eQqaa(N) = 0·98(6) and eQqbb(N) = -4·78(22) MHz. The quadrupole coupling values are discussed in relation to results in other small molecules and nitrosyl complexes. Rotational constants obtained from the measurements were B = 5737·70(6) and C = 5376·32(6) MHz.

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VL - 76

SP - 221

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JO - Molecular Physics

JF - Molecular Physics

IS - 1

ER -

Quadrupole coupling measurements on³⁵CINO

Abstract

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