Quadrupole coupling measurements on IF5

J. C. Shea; S. G. Kukolich

doi:10.1016/0009-2614(90)85149-7

Quadrupole coupling measurements on IF₅

J. C. Shea, S. G. Kukolich

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

High resolution spectra of J=0→1, 1→2 and 2→3 rotational transitions in IF₅ were obtained using a Flygare-Balle-type microwave spectrometer. Twenty-two transitions with K=0 or K=1 were fit to obtain the molecular parameters A₀=B₀=2727.4231 (8) MHz, eq_ccQ=1069.41 (4) and the spin-rotation interaction C_C=0.016(1) MHz.

Original language	English (US)
Pages (from-to)	489-492
Number of pages	4
Journal	Chemical Physics Letters
Volume	168
Issue number	5
DOIs	https://doi.org/10.1016/0009-2614(90)85149-7
State	Published - May 11 1990

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/0009-2614(90)85149-7

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title = "Quadrupole coupling measurements on IF5",

abstract = "High resolution spectra of J=0→1, 1→2 and 2→3 rotational transitions in IF5 were obtained using a Flygare-Balle-type microwave spectrometer. Twenty-two transitions with K=0 or K=1 were fit to obtain the molecular parameters A0=B0=2727.4231 (8) MHz, eqccQ=1069.41 (4) and the spin-rotation interaction CC=0.016(1) MHz.",

author = "Shea, {J. C.} and Kukolich, {S. G.}",

note = "Funding Information: Partials upportfo r this researchw asp rovidedb y a ResearchC orporation,R esearchO pportunities Award to SGK. Acknowledgemeinst madet o the donorso f the PetroleumR esearchF und, adminis-teredb y theA mericanC hemicaSl ocietyf,o r partial support of this research.W e thank Dr. Roger Bumgamefro r the symmetric-topq,u adrupoleco u-plingf ittingp rogram.",

year = "1990",

month = may,

day = "11",

doi = "10.1016/0009-2614(90)85149-7",

language = "English (US)",

volume = "168",

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journal = "Chemical Physics Letters",

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publisher = "Elsevier B.V.",

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AU - Shea, J. C.

AU - Kukolich, S. G.

N1 - Funding Information: Partials upportfo r this researchw asp rovidedb y a ResearchC orporation,R esearchO pportunities Award to SGK. Acknowledgemeinst madet o the donorso f the PetroleumR esearchF und, adminis-teredb y theA mericanC hemicaSl ocietyf,o r partial support of this research.W e thank Dr. Roger Bumgamefro r the symmetric-topq,u adrupoleco u-plingf ittingp rogram.

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Y1 - 1990/5/11

N2 - High resolution spectra of J=0→1, 1→2 and 2→3 rotational transitions in IF5 were obtained using a Flygare-Balle-type microwave spectrometer. Twenty-two transitions with K=0 or K=1 were fit to obtain the molecular parameters A0=B0=2727.4231 (8) MHz, eqccQ=1069.41 (4) and the spin-rotation interaction CC=0.016(1) MHz.

AB - High resolution spectra of J=0→1, 1→2 and 2→3 rotational transitions in IF5 were obtained using a Flygare-Balle-type microwave spectrometer. Twenty-two transitions with K=0 or K=1 were fit to obtain the molecular parameters A0=B0=2727.4231 (8) MHz, eqccQ=1069.41 (4) and the spin-rotation interaction CC=0.016(1) MHz.

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Quadrupole coupling measurements on IF₅

Abstract

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