Propentdyopent: The scaffold of a heme metabolite as an electron reservoir in transition metal complexes

R. Gautam; T. M. Chang; A. V. Astashkin; K. M. Lincoln; E. Tomat

doi:10.1039/c6cc01961g

Propentdyopent: The scaffold of a heme metabolite as an electron reservoir in transition metal complexes

R. Gautam, T. M. Chang, A. V. Astashkin, K. M. Lincoln, E. Tomat

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The dipyrrin-1,9-dione scaffold of heme metabolite propendyopent coordinates late transition metals (Co, Ni, Cu, and Zn) forming homoleptic, pseudo-tetrahedral complexes. Electrochemical and spectroscopic studies reveal that the monoanionic, bidentate ligands behave as electron reservoirs as the complexes reversibly host one or two ligand-based radicals.

Original language	English (US)
Pages (from-to)	6585-6588
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	39
DOIs	https://doi.org/10.1039/c6cc01961g
State	Published - 2016
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
General Chemistry
Catalysis

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10.1039/c6cc01961g

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abstract = "The dipyrrin-1,9-dione scaffold of heme metabolite propendyopent coordinates late transition metals (Co, Ni, Cu, and Zn) forming homoleptic, pseudo-tetrahedral complexes. Electrochemical and spectroscopic studies reveal that the monoanionic, bidentate ligands behave as electron reservoirs as the complexes reversibly host one or two ligand-based radicals.",

author = "R. Gautam and Chang, {T. M.} and Astashkin, {A. V.} and Lincoln, {K. M.} and E. Tomat",

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year = "2016",

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AU - Astashkin, A. V.

AU - Lincoln, K. M.

AU - Tomat, E.

PY - 2016

Y1 - 2016

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AB - The dipyrrin-1,9-dione scaffold of heme metabolite propendyopent coordinates late transition metals (Co, Ni, Cu, and Zn) forming homoleptic, pseudo-tetrahedral complexes. Electrochemical and spectroscopic studies reveal that the monoanionic, bidentate ligands behave as electron reservoirs as the complexes reversibly host one or two ligand-based radicals.

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Propentdyopent: The scaffold of a heme metabolite as an electron reservoir in transition metal complexes

Abstract

ASJC Scopus subject areas

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CCDC 1434495: Experimental Crystal Structure Determination

CCDC 1434496: Experimental Crystal Structure Determination

CCDC 1431605: Experimental Crystal Structure Determination

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Propentdyopent: The scaffold of a heme metabolite as an electron reservoir in transition metal complexes

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 1434495: Experimental Crystal Structure Determination

CCDC 1434496: Experimental Crystal Structure Determination

CCDC 1431605: Experimental Crystal Structure Determination

Cite this