Abstract
The strength of a bond, defined as p=s/r, where s is the Pauling bond strength and r is the row number of an M cation bonded to an oxide anion, is related to a build-up of electron density along the MO bonds in a relatively large number of oxide and hydroxyacid molecules, three oxide minerals and three molecular crystals. As p increases, the value of the electron density is observed to increase at the bond critical points with the lengths of the bonds shortening and the electronegativities of the M cations bonded to the oxide anion increasing. The assertion that the covalency of a bond is intrinsically connected to its bond strength is supported by the electron density distribution and its bond critical point properties. A connection also exists between the properties of the electron density distributions and the connectivity of the bond strength network formed by the bonded atoms of a structure.
Original language | English (US) |
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Pages (from-to) | 585-590 |
Number of pages | 6 |
Journal | Physics and Chemistry of Minerals |
Volume | 25 |
Issue number | 8 |
DOIs | |
State | Published - 1998 |
ASJC Scopus subject areas
- General Materials Science
- Geochemistry and Petrology