Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle

Jonathan L. Sessler; Elisa Tomat; Vincent M. Lynch

doi:10.1021/ja0582004

Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle

Jonathan L. Sessler, Elisa Tomat, Vincent M. Lynch

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

82 Scopus citations

Abstract

The binuclear silver(I) complex of a Schiff base oligopyrrolic macrocycle was prepared in high yield and fully characterized. UV-visible absorption and 1H NMR spectroscopic analyses reveal that coordination of Ag(I) cations is subject to a strong positive homotropic allosteric effect.

Original language	English (US)
Pages (from-to)	4184-4185
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	13
DOIs	https://doi.org/10.1021/ja0582004
State	Published - Apr 5 2006

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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title = "Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle",

abstract = "The binuclear silver(I) complex of a Schiff base oligopyrrolic macrocycle was prepared in high yield and fully characterized. UV-visible absorption and 1H NMR spectroscopic analyses reveal that coordination of Ag(I) cations is subject to a strong positive homotropic allosteric effect.",

author = "Sessler, {Jonathan L.} and Elisa Tomat and Lynch, {Vincent M.}",

year = "2006",

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doi = "10.1021/ja0582004",

language = "English (US)",

volume = "128",

pages = "4184--4185",

journal = "Journal of the American Chemical Society",

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T1 - Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle

AU - Sessler, Jonathan L.

AU - Tomat, Elisa

AU - Lynch, Vincent M.

PY - 2006/4/5

Y1 - 2006/4/5

N2 - The binuclear silver(I) complex of a Schiff base oligopyrrolic macrocycle was prepared in high yield and fully characterized. UV-visible absorption and 1H NMR spectroscopic analyses reveal that coordination of Ag(I) cations is subject to a strong positive homotropic allosteric effect.

AB - The binuclear silver(I) complex of a Schiff base oligopyrrolic macrocycle was prepared in high yield and fully characterized. UV-visible absorption and 1H NMR spectroscopic analyses reveal that coordination of Ag(I) cations is subject to a strong positive homotropic allosteric effect.

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AN - SCOPUS:33645469329

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 13

ER -

Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle

Abstract

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