Photoelectron imaging was used to study molecular and cluster anions on the examples of CS2- and OCS-(H2O)1,2. Results for OCS-(H2O)1,2 were compared to that of CS2-. The adiabatic electron affinity of OCS was estimated at -0.04 eV, while the VDEs of OCS-·H2 and OCS- were determined to be 2.07±0.07 and 2.53±0.07 eV, respectively.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry