Photoelectron imaging spectroscopy of molecular and cluster anions: CS2- and OCS- (H2O)1,2

Eric Surber; Andrei Sanov

doi:10.1063/1.1467916

Photoelectron imaging spectroscopy of molecular and cluster anions: CS₂^- and OCS^- (H₂O)_1,2

Eric Surber, Andrei Sanov

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Abstract

Photoelectron imaging was used to study molecular and cluster anions on the examples of CS₂^- and OCS^-(H₂O)_1,2. Results for OCS^-(H₂O)_1,2 were compared to that of CS₂^-. The adiabatic electron affinity of OCS was estimated at -0.04 eV, while the VDEs of OCS^-·H₂ and OCS^- were determined to be 2.07±0.07 and 2.53±0.07 eV, respectively.

Original language	English (US)
Pages (from-to)	5921-5924
Number of pages	4
Journal	Journal of Chemical Physics
Volume	116
Issue number	14
DOIs	https://doi.org/10.1063/1.1467916
State	Published - Apr 8 2002

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "Photoelectron imaging was used to study molecular and cluster anions on the examples of CS2- and OCS-(H2O)1,2. Results for OCS-(H2O)1,2 were compared to that of CS2-. The adiabatic electron affinity of OCS was estimated at -0.04 eV, while the VDEs of OCS-·H2 and OCS- were determined to be 2.07±0.07 and 2.53±0.07 eV, respectively.",

author = "Eric Surber and Andrei Sanov",

year = "2002",

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doi = "10.1063/1.1467916",

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T2 - CS2- and OCS- (H2O)1,2

AU - Surber, Eric

AU - Sanov, Andrei

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Y1 - 2002/4/8

N2 - Photoelectron imaging was used to study molecular and cluster anions on the examples of CS2- and OCS-(H2O)1,2. Results for OCS-(H2O)1,2 were compared to that of CS2-. The adiabatic electron affinity of OCS was estimated at -0.04 eV, while the VDEs of OCS-·H2 and OCS- were determined to be 2.07±0.07 and 2.53±0.07 eV, respectively.

AB - Photoelectron imaging was used to study molecular and cluster anions on the examples of CS2- and OCS-(H2O)1,2. Results for OCS-(H2O)1,2 were compared to that of CS2-. The adiabatic electron affinity of OCS was estimated at -0.04 eV, while the VDEs of OCS-·H2 and OCS- were determined to be 2.07±0.07 and 2.53±0.07 eV, respectively.

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Photoelectron imaging spectroscopy of molecular and cluster anions: CS₂^- and OCS^- (H₂O)_1,2

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