Photoelectron imaging of carbonyl sulfide cluster anions: Isomer coexistence and competition of excited-state decay mechanisms

Eric Surber; Andrei Sanov

doi:10.1063/1.1569915

Photoelectron imaging of carbonyl sulfide cluster anions: Isomer coexistence and competition of excited-state decay mechanisms

Eric Surber, Andrei Sanov

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

An attempt was made to decipher the structure of (OCS)_n^- cluster anions using photoelectron spectroscopy. The employed imaging approach allowed the simultaneous examination of energy spectra and angular distributions of both fast and slow photoelectrons. The results provide evidence of the coexistence of electronic and structural isomers of (OCS)_n^- with the OCS^- and covalently bound (OCS)₂^- cluster cores.

Original language	English (US)
Pages (from-to)	9192-9200
Number of pages	9
Journal	Journal of Chemical Physics
Volume	118
Issue number	20
DOIs	https://doi.org/10.1063/1.1569915
State	Published - May 22 2003

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.1569915

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title = "Photoelectron imaging of carbonyl sulfide cluster anions: Isomer coexistence and competition of excited-state decay mechanisms",

abstract = "An attempt was made to decipher the structure of (OCS)n- cluster anions using photoelectron spectroscopy. The employed imaging approach allowed the simultaneous examination of energy spectra and angular distributions of both fast and slow photoelectrons. The results provide evidence of the coexistence of electronic and structural isomers of (OCS)n- with the OCS- and covalently bound (OCS)2- cluster cores.",

author = "Eric Surber and Andrei Sanov",

year = "2003",

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AU - Sanov, Andrei

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AB - An attempt was made to decipher the structure of (OCS)n- cluster anions using photoelectron spectroscopy. The employed imaging approach allowed the simultaneous examination of energy spectra and angular distributions of both fast and slow photoelectrons. The results provide evidence of the coexistence of electronic and structural isomers of (OCS)n- with the OCS- and covalently bound (OCS)2- cluster cores.

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Photoelectron imaging of carbonyl sulfide cluster anions: Isomer coexistence and competition of excited-state decay mechanisms

Abstract

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