Photoelectrochemical effects and (photo)conductivity of "n-type" phthalocyanines

E. Karmann; J. P. Meyer; D. Schlettwein; N. I. Jaeger; M. Anderson; A. Schmidt; N. R. Armstrong

doi:10.1080/10587259608037901

Photoelectrochemical effects and (photo)conductivity of "n-type" phthalocyanines

E. Karmann, J. P. Meyer, D. Schlettwein, N. I. Jaeger, M. Anderson, A. Schmidt, N. R. Armstrong

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

In vacuo thin films of the phthalocyanine derivatives TPyTAPZn and F₁₆PcZn show n-type behavior in thermopower and conductivity measurements. After exposure to air the properties are changed characteristically. Photoelectrochemical experiments show that while TPyTAPZn still behaves like an n-type semiconductor, F₁₆PcZn exhibits the properties of a photoconductor. Time-dependent measurements give further insight into the differences between the two materials in their interaction with gaseous dopants. The results are discussed in terms of different positions of the HOMO- and LUMO-orbitals of TPyTAPZn and F₁₆PcZn taken from UPS-measurements.

Original language	English (US)
Pages (from-to)	283-291
Number of pages	9
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	283
DOIs	https://doi.org/10.1080/10587259608037901
State	Published - 1996
Externally published	Yes

ASJC Scopus subject areas

Condensed Matter Physics

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title = "Photoelectrochemical effects and (photo)conductivity of {"}n-type{"} phthalocyanines",

abstract = "In vacuo thin films of the phthalocyanine derivatives TPyTAPZn and F16PcZn show n-type behavior in thermopower and conductivity measurements. After exposure to air the properties are changed characteristically. Photoelectrochemical experiments show that while TPyTAPZn still behaves like an n-type semiconductor, F16PcZn exhibits the properties of a photoconductor. Time-dependent measurements give further insight into the differences between the two materials in their interaction with gaseous dopants. The results are discussed in terms of different positions of the HOMO- and LUMO-orbitals of TPyTAPZn and F16PcZn taken from UPS-measurements.",

author = "E. Karmann and Meyer, {J. P.} and D. Schlettwein and Jaeger, {N. I.} and M. Anderson and A. Schmidt and Armstrong, {N. R.}",

note = "Funding Information: Acknowledment The authors are gratehl to D. Wohrle for fnrithl discussions and S. Hiller for the synthesis of F&Zn as well as to the University of Bremen (FNK NFSP2/90, FNK 02/778/5) and the State of Bremen for financial support.",

year = "1996",

doi = "10.1080/10587259608037901",

language = "English (US)",

volume = "283",

pages = "283--291",

journal = "Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

publisher = "Taylor and Francis Ltd.",

}

TY - JOUR

T1 - Photoelectrochemical effects and (photo)conductivity of "n-type" phthalocyanines

AU - Karmann, E.

AU - Meyer, J. P.

AU - Schlettwein, D.

AU - Jaeger, N. I.

AU - Anderson, M.

AU - Schmidt, A.

AU - Armstrong, N. R.

N1 - Funding Information: Acknowledment The authors are gratehl to D. Wohrle for fnrithl discussions and S. Hiller for the synthesis of F&Zn as well as to the University of Bremen (FNK NFSP2/90, FNK 02/778/5) and the State of Bremen for financial support.

PY - 1996

Y1 - 1996

N2 - In vacuo thin films of the phthalocyanine derivatives TPyTAPZn and F16PcZn show n-type behavior in thermopower and conductivity measurements. After exposure to air the properties are changed characteristically. Photoelectrochemical experiments show that while TPyTAPZn still behaves like an n-type semiconductor, F16PcZn exhibits the properties of a photoconductor. Time-dependent measurements give further insight into the differences between the two materials in their interaction with gaseous dopants. The results are discussed in terms of different positions of the HOMO- and LUMO-orbitals of TPyTAPZn and F16PcZn taken from UPS-measurements.

AB - In vacuo thin films of the phthalocyanine derivatives TPyTAPZn and F16PcZn show n-type behavior in thermopower and conductivity measurements. After exposure to air the properties are changed characteristically. Photoelectrochemical experiments show that while TPyTAPZn still behaves like an n-type semiconductor, F16PcZn exhibits the properties of a photoconductor. Time-dependent measurements give further insight into the differences between the two materials in their interaction with gaseous dopants. The results are discussed in terms of different positions of the HOMO- and LUMO-orbitals of TPyTAPZn and F16PcZn taken from UPS-measurements.

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DO - 10.1080/10587259608037901

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VL - 283

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JO - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

ER -

Photoelectrochemical effects and (photo)conductivity of "n-type" phthalocyanines

Abstract

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