Photo-initiation of intermolecular bonding and oxide deposition in Ti-based alkoxide solutions

B. G. Potter; J. D. Musgraves; T. J. Boyle

doi:10.1016/j.jnoncrysol.2007.12.001

Photo-initiation of intermolecular bonding and oxide deposition in Ti-based alkoxide solutions

B. G. Potter, J. D. Musgraves, T. J. Boyle

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Photoexposure of a water-stable, Ti-alkoxide, (OC₆H₆N)₂Ti(OC₆H₂(CH₂N(CH₃)₂)₃-2,4,6)₂, dissolved in a water/pyridine solution yielded an insoluble, solid phase, present in the form of suspended particles and a deposited material on the vertical side-wall of the solution container. Raman analysis of these photoproducts confirmed the UV-initiation of hydrolysis and condensation reactions in the alkoxide reagent. The excitation wavelength dependence of the photostructural effects observed provides insight into the mechanisms contributing to these photoinduced phenomena. The results are extended to enable the photopatterned deposition of physical relief structures directly from solution in this system.

Original language	English (US)
Pages (from-to)	2017-2022
Number of pages	6
Journal	Journal of Non-Crystalline Solids
Volume	354
Issue number	18
DOIs	https://doi.org/10.1016/j.jnoncrysol.2007.12.001
State	Published - Apr 15 2008

Keywords

Films and coatings
Laser-matter interactions
Organic-inorganic hybrids
Polymers and organics
Sol-gels (xerogels)

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Materials Chemistry

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10.1016/j.jnoncrysol.2007.12.001

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@article{236c193dee7e4963a48930f8a34e8b1a,

title = "Photo-initiation of intermolecular bonding and oxide deposition in Ti-based alkoxide solutions",

abstract = "Photoexposure of a water-stable, Ti-alkoxide, (OC6H6N)2Ti(OC6H2(CH2N(CH3)2)3-2,4,6)2, dissolved in a water/pyridine solution yielded an insoluble, solid phase, present in the form of suspended particles and a deposited material on the vertical side-wall of the solution container. Raman analysis of these photoproducts confirmed the UV-initiation of hydrolysis and condensation reactions in the alkoxide reagent. The excitation wavelength dependence of the photostructural effects observed provides insight into the mechanisms contributing to these photoinduced phenomena. The results are extended to enable the photopatterned deposition of physical relief structures directly from solution in this system.",

keywords = "Films and coatings, Laser-matter interactions, Organic-inorganic hybrids, Polymers and organics, Sol-gels (xerogels)",

author = "Potter, \{B. G.\} and Musgraves, \{J. D.\} and Boyle, \{T. J.\}",

note = "Funding Information: The authors would like to acknowledge the valuable contributions of K. Simmons-Potter and Z. Schneider of the University of Arizona. Research was supported by the Department of Energy, Office of Basic Energy Sciences and the State of Arizona TRIF Optics Initiative. Sandia is a multi-program laboratory operated by Sandia Corporation, a Lockheed–Martin Company, for the United States Department of Energy under contract number DE-AC04-94AL85000.",

year = "2008",

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day = "15",

doi = "10.1016/j.jnoncrysol.2007.12.001",

language = "English (US)",

volume = "354",

pages = "2017--2022",

journal = "Journal of Non-Crystalline Solids",

issn = "0022-3093",

publisher = "Elsevier B.V.",

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}

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T1 - Photo-initiation of intermolecular bonding and oxide deposition in Ti-based alkoxide solutions

AU - Potter, B. G.

AU - Musgraves, J. D.

AU - Boyle, T. J.

N1 - Funding Information: The authors would like to acknowledge the valuable contributions of K. Simmons-Potter and Z. Schneider of the University of Arizona. Research was supported by the Department of Energy, Office of Basic Energy Sciences and the State of Arizona TRIF Optics Initiative. Sandia is a multi-program laboratory operated by Sandia Corporation, a Lockheed–Martin Company, for the United States Department of Energy under contract number DE-AC04-94AL85000.

PY - 2008/4/15

Y1 - 2008/4/15

N2 - Photoexposure of a water-stable, Ti-alkoxide, (OC6H6N)2Ti(OC6H2(CH2N(CH3)2)3-2,4,6)2, dissolved in a water/pyridine solution yielded an insoluble, solid phase, present in the form of suspended particles and a deposited material on the vertical side-wall of the solution container. Raman analysis of these photoproducts confirmed the UV-initiation of hydrolysis and condensation reactions in the alkoxide reagent. The excitation wavelength dependence of the photostructural effects observed provides insight into the mechanisms contributing to these photoinduced phenomena. The results are extended to enable the photopatterned deposition of physical relief structures directly from solution in this system.

AB - Photoexposure of a water-stable, Ti-alkoxide, (OC6H6N)2Ti(OC6H2(CH2N(CH3)2)3-2,4,6)2, dissolved in a water/pyridine solution yielded an insoluble, solid phase, present in the form of suspended particles and a deposited material on the vertical side-wall of the solution container. Raman analysis of these photoproducts confirmed the UV-initiation of hydrolysis and condensation reactions in the alkoxide reagent. The excitation wavelength dependence of the photostructural effects observed provides insight into the mechanisms contributing to these photoinduced phenomena. The results are extended to enable the photopatterned deposition of physical relief structures directly from solution in this system.

KW - Films and coatings

KW - Laser-matter interactions

KW - Organic-inorganic hybrids

KW - Polymers and organics

KW - Sol-gels (xerogels)

UR - https://www.scopus.com/pages/publications/40649115184

UR - https://www.scopus.com/inward/citedby.url?scp=40649115184&partnerID=8YFLogxK

U2 - 10.1016/j.jnoncrysol.2007.12.001

DO - 10.1016/j.jnoncrysol.2007.12.001

M3 - Article

AN - SCOPUS:40649115184

SN - 0022-3093

VL - 354

SP - 2017

EP - 2022

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 18

ER -

Photo-initiation of intermolecular bonding and oxide deposition in Ti-based alkoxide solutions

Abstract

Keywords

ASJC Scopus subject areas

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